in acetonitrile T=50°C; aminolysis of phenyl dithioacetates with anilines, N,N-dimethylanilines and benzylamines in MeCN; formation of zwitterionic tetrahedral intermediate; proton transfer; rate-limiting step; effect of nucleophile, leaving group; Rate constantMechanismProduct distribution;
参考文献
Journal of Organic Chemistry, , vol. 62, # 17 p. 5780 - 5784
in acetonitrile T=50°C; aminolysis of phenyl dithioacetates with anilines, N,N-dimethylanilines and benzylamines in MeCN; formation of zwitterionic tetrahedral intermediate; proton transfer; rate-limiting step; effect of nucleophile, leaving group; Rate constantMechanism;
参考文献
Journal of Organic Chemistry, , vol. 62, # 17 p. 5780 - 5784
in acetonitrile T=50°C; aminolysis of phenyl dithioacetates with anilines, N,N-dimethylanilines and benzylamines in MeCN; formation of zwitterionic tetrahedral intermediate; proton transfer; rate-limiting step; effect of nucleophile, leaving group; Rate constantMechanism;
参考文献
Journal of Organic Chemistry, , vol. 62, # 17 p. 5780 - 5784
in acetonitrile T=50°C; aminolysis of phenyl dithioacetates with anilines, N,N-dimethylanilines and benzylamines in MeCN; formation of zwitterionic tetrahedral intermediate; proton transfer; rate-limiting step; effect of nucleophile, leaving group; Rate constantMechanism;
参考文献
Journal of Organic Chemistry, , vol. 62, # 17 p. 5780 - 5784
