1,1,2,2-四苯基乙烷合成路线 （共 396 条）
反应条件
acetic acid in tetrahydrofuran
byproducts: carbon monoxide, C5H6; under N2, THF suspn. of V-complex reacted with CH3CO2H; elem. anal.;
参考文献
Gambarotta, Sandro; Pasquali, Marco; Floriani, Carlo; Chiesi-Villa, Angiola; Guastini, Carlo
Inorganic Chemistry, 1981 , vol. 20, p. 1173 - 1178
反应条件
diethyl sodio phosphonate in benzene
T=180°C; 8 h; sealed tube;
参考文献
Minami, Toru; Matsuzaki, Narihide; Ohshiro, Yoshiki; Agawa, Toshio
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 1731 - 1738
反应条件
n-butyllithium in tetrahydrofuran; hexane
T=-20°C; 4 h; Yields of byproduct given;
参考文献
Furukawa, Mitsuru; Okawara, Tadashi; Noguchi, Yoshihide; Nishikawa, Masumi; Tomimatsu, Masahide
Chemical and Pharmaceutical Bulletin, 1980 , vol. 28, # 3 p. 976 - 978
反应条件
dipotassium hydrogenphosphate; silver nitrate; zinc in water
T=30°C; 1 h;
参考文献
Bieber, Lothar W.; Storch, Elisabeth C.; Malvestiti, Ivani; Da Silva, Margarete F.
Tetrahedron Letters, 1998 , vol. 39, # 51 p. 9393 - 9396
反应条件
1: Bromure de phenyl magnesium With manganese (II) chloride in tetrahydrofuran
Metallation;
2: 5-tetrakis (dibromomethyl)-benzene in tetrahydrofuran
Substitution;
参考文献
Kakiya; Shinokubo; Oshima
Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 9 p. 2139 - 2147
反应条件
palladium diacetate; caesium carbonate; triphenylphosphine in o-xylene
20 h; Heating;
参考文献
Wakui, Hiroyuki; Kawasaki, Satoshi; Satoh, Tetsuya; Miura, Masahiro; Nomura, Masakatsu
Journal of the American Chemical Society, 2004 , vol. 126, # 28 p. 8658 - 8659
反应条件
1: Et3N / CH2Cl2 / 1.) 0 deg C, 3 h, 2.) r.t., 1 h
2: MsN3, Et3N / acetonitrile; H2O / 12 h / Ambient temperature
3: 19 percent / Cu / toluene / 2 h / Heating
View Scheme
参考文献
West; Naidu
Journal of Organic Chemistry, 1994 , vol. 59, # 20 p. 6051 - 6056
反应条件
formic acid in tetrahydrofuran
byproducts: carbon monoxide, C5H6; under N2, THF suspn. of V-complex reacted with 97percent HCO2H; stood overnight; elem. anal.;
参考文献
Gambarotta, Sandro; Pasquali, Marco; Floriani, Carlo; Chiesi-Villa, Angiola; Guastini, Carlo
Inorganic Chemistry, 1981 , vol. 20, p. 1173 - 1178
反应条件
n-butyllithium in tetrahydrofuran; hexane
T=-20°C; 4 h;
参考文献
Furukawa, Mitsuru; Okawara, Tadashi; Noguchi, Yoshihide; Nishikawa, Masumi; Tomimatsu, Masahide
Chemical and Pharmaceutical Bulletin, 1980 , vol. 28, # 3 p. 976 - 978
反应条件
acetic acid; mercury; zinc
2 h; Heating;
参考文献
Vona, Maria Luisa Di; Rosnati, Vittorio
Journal of Organic Chemistry, 1991 , vol. 56, # 13 p. 4269 - 4273
