1-(4-氯苯基)-2-硝基苯合成路线 （共 31 条）
反应条件
10 palladium on activated carbon; hydrogen in methanol T=40°C; P=37503.8 Torr;
参考文献
Glasnov, Toma N.; Kappe, C. Oliver
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 17 p. 3089 - 3097
反应条件
iron (III) acetylacetonate; hydrazine hydrate in methanol T=150°C; Microwave irradiationGreen chemistry;
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 40 p. 10190 - 10193
反应条件
10 palladium on activated carbon; hydrogen in methanol T=40°C; P=37503.8 Torr;
参考文献
Advanced Synthesis and Catalysis, , vol. 352, # 17 p. 3089 - 3097
反应条件
C21H28N2; potassium carbonate; palladium dichloride in water; N,N-dimethyl-formamide
T=110°C; Suzuki-Miyaura Coupling; 4 h;
参考文献
Cao, Gao; Yang, Hai-Qing; Luo, Bao-Tian; Liu, Feng-Shou
Journal of Organometallic Chemistry, 2013 , vol. 745-746, p. 158 - 165
反应条件
potassium carbonate; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; water
8 h; Inert atmosphereReflux;
参考文献
TOSOH CORPORATION
Patent: US2012/203010 A1, 2012 ;
Location in patent: Page/Page column 33 ;
反应条件
2,6-dimethylpyridine; triphenylphosphine; silver carbonate; palladium dichloride in 1-methyl-pyrrolidin-2-one
T=130°C; 16 h; Inert atmosphere;
参考文献
Goossen, Lukas J.; Lange, Paul P.; Rodriguez, Nuria; Linder, Christophe
Chemistry - A European Journal, 2010 , vol. 16, # 13 p. 3906 - 3909
反应条件
1: ortho-nitrobenzoic acid With cupric(II) carbonate in various solvent(s)
T=120°C; 0.5 h;
2: 1-chloro-4-bromobenzene With potassium fluoride; triphenylphosphine; palladium acetylacetonate in various solvent(s)
T=120°C; 24 h; Further stages.;
参考文献
Goossen, Lukas J.; Rodriguez, Nuria; Melzer, Bettina; Linder, Christophe; Deng, Guojun; Levy, Laura M.
Journal of the American Chemical Society, 2007 , vol. 129, # 15 p. 4824 - 4833
反应条件
1: ortho-nitrobenzoic acid With potassium carbonate in various solvent(s)
T=120°C; 0.5 h;
2: para-dichlorobenzene With 1,10-phenanthroline; copper(l) iodide in various solvent(s)
T=160°C; 24 h; Further stages.;
参考文献
Goossen, Lukas J.; Rodriguez, Nuria; Melzer, Bettina; Linder, Christophe; Deng, Guojun; Levy, Laura M.
Journal of the American Chemical Society, 2007 , vol. 129, # 15 p. 4824 - 4833
反应条件
1: ortho-nitrobenzoic acid With potassium carbonate in various solvent(s)
T=120°C; 0.5 h;
2: 1-chloro-4-bromobenzene With 1,10-phenanthroline; copper(l) iodide in various solvent(s)
T=160°C; 24 h; Further stages.;
参考文献
Goossen, Lukas J.; Rodriguez, Nuria; Melzer, Bettina; Linder, Christophe; Deng, Guojun; Levy, Laura M.
Journal of the American Chemical Society, 2007 , vol. 129, # 15 p. 4824 - 4833
反应条件
manganese(IV) oxide; potassium tert-butylate in N,N-dimethyl-formamide
T=60°C; 6 h;
参考文献
BASF SE; KORTE, Alexander; LOHMANN, Jan Klaas; GROTE, Thomas; EBEL, Klaus; ZIERKE, Thomas; MAYER, Horst; WAZULEK, Ralf
Patent: WO2010/102980 A1, 2010 ;
Location in patent: Page/Page column 41 ;
