3,4-二乙基-3,4-二苯基己烷合成路线 （共 8 条）
反应条件
hydrogen bromide; acetic acid; zinc
T=0°C; Title compound not separated from byproducts;
参考文献
Kratt, Guenter; Beckhaus, Hans-Dieter; Lindner, Hans Joerg; Ruechardt, Christoph
Chemische Berichte, 1983 , vol. 116, # 9 p. 3235 - 3263
反应条件
VCl2(N,N,N',N'-tetramethylethylenediamine)2; oxygen
1) THF, 20 deg C, 1 h; 2) THF, reflux, 15 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kataoka, Yasutaka; Akiyama, Hiroaki; Makihira, Isamu; Tani, Kazuhide
Journal of Organic Chemistry, 1996 , vol. 61, # 18 p. 6094 - 6095
反应条件
1: 1) Mg / 1) THF, 0.5 h, 2) 0.5 h
2: 1) HBr, 2) Zn / 1) AcOH, 0 deg C, 1.5 h, 2) 5 deg C -> room temp.
View Scheme
参考文献
Maslak, Przemyslaw; Narvaez, Javier N.; Kula, Jozef; Malinski, David S.
Journal of Organic Chemistry, 1990 , vol. 55, # 15 p. 4550 - 4559
反应条件
1: 1) Mg / 1) THF, 0.5 h, 2) 0.5 h
2: 1) HBr, 2) Zn / 1) AcOH, 0 deg C, 1.5 h, 2) 5 deg C -> room temp.
View Scheme
参考文献
Maslak, Przemyslaw; Narvaez, Javier N.; Kula, Jozef; Malinski, David S.
Journal of Organic Chemistry, 1990 , vol. 55, # 15 p. 4550 - 4559
反应条件
hydrogen bromide; acetic acid; zinc
参考文献
Ziegler; Deparade
Justus Liebigs Annalen der Chemie, 1950 , vol. 567, p. 123,136
反应条件
VCl2(N,N,N',N'-tetramethylethylenediamine)2; allyl bromide
1.) THF, 20 deg C, 1 h, 2.) 20 deg C, 1 h, reflux, 12 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kataoka, Yasutaka; Makihira, Isamu; Akiyama, Hiroaki; Tani, Kazuhide
Tetrahedron, 1997 , vol. 53, # 28 p. 9525 - 9540
反应条件
VCl2(N,N,N',N'-tetramethylethylenediamine)2
1.) THF, 20 deg C, 1 h, 2.) 20 deg C, 1 h, reflux, 12 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kataoka, Yasutaka; Makihira, Isamu; Akiyama, Hiroaki; Tani, Kazuhide
Tetrahedron, 1997 , vol. 53, # 28 p. 9525 - 9540
反应条件
n-tetradec-1l-ene; thiophenol
T=176°C;
参考文献
Maslak, Przemyslaw; Narvaez, Javier N.; Kula, Jozef; Malinski, David S.
Journal of Organic Chemistry, 1990 , vol. 55, # 15 p. 4550 - 4559
