3-乙氧基-5,5-二甲基-2-环己烯-1-酮合成路线 （共 26 条）
反应条件
1: 91 percent / LiAlH4 2: 91 percent / LiAlH4 3: 81 percent / propionic acid / 36 h / 138 °C View Scheme
参考文献
Wawrzenczyk, Czeslaw; Lochynski, Stanislaw
Monatshefte fuer Chemie, 1985 , vol. 116, p. 99 - 110
反应条件
1: 91 percent / LiAlH4 2: 91 percent / LiAlH4 3: 81 percent / propionic acid / 36 h / 138 °C 4: LiAlH4 5: 74 percent / C5H5N View Scheme
参考文献
Wawrzenczyk, Czeslaw; Lochynski, Stanislaw
Monatshefte fuer Chemie, 1985 , vol. 116, p. 99 - 110
反应条件
methyl-magnesium iodide; diethyl ether
参考文献
Frank; Hall
Journal of the American Chemical Society, 1950 , vol. 72, p. 1645,1646
反应条件
3,3-dimethyldioxirane in dichloromethane; acetone T=-20°C; 26 h;
参考文献
Adam, Waldemar; Hadjiarapoglou, Lazaros
Chemische Berichte, 1990 , vol. 123, # 10 p. 2077 - 2079
反应条件
ammonium cerium(IV) nitrate in water; acetonitrile 0.5 h; Heating;
参考文献
Banerjee, Biplab; Mandal, Samir Kumar; Roy, Subhas Chandra
Chemistry Letters, 2006 , vol. 35, # 1 p. 16 - 17
反应条件
1: 98 percent / lithium aluminum hydride / diethyl ether / 1 h / Ambient temperature 2: 90 percent / 35percent H2O2, NaOH / methanol / 0.17 h / 15 - 36 °C View Scheme
参考文献
Bergman, Rolf; Magnusson, Goeran
Journal of Organic Chemistry, 1986 , vol. 51, # 2 p. 212 - 217
反应条件
toluene-4-sulfonic acid in benzene
6 h; Reflux;
参考文献
Winska, Katarzyna; Grudniewska, Aleksandra; Chojnacka, Anna; Bialonska, Agata; Wawrzenczyk, Czeslaw
Tetrahedron Asymmetry, 2010 , vol. 21, # 6 p. 670 - 678
反应条件
in ethanol
0.333333 h; Heating / reflux;
参考文献
UCB PHARMA S.A.
Patent: WO2009/71890 A1, 2009 ;
Location in patent: Page/Page column 100 ;
WO 2009/071890 A1
参考文献
Hayasi,Y. et al.
Bulletin of the Chemical Society of Japan, 1970 , vol. 43, p. 2506 - 2511
反应条件
triethylamine in pyridine
2 h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Music, Irena; Golobic, Amalija; Vercek, Bojan
Heterocycles, 1998 , vol. 48, # 2 p. 353 - 358
