[3-甲基-5-(2,6,6-三甲基-1-环己烯-1-基)-2,4-戊二烯基]三苯基溴化鏻合成路线 （共 14 条）
反应条件
1: 4-(2,6,6-trimethyl-1-cyclohexenyl-1-yl)-3-buten-2-one; vinyl-magnesium bromide
2: triphenylphosphine hydrobromide Further stages.;
参考文献
Li, Haibing; Morin, Christophe
Tetrahedron Letters, 2004 , vol. 45, # 29 p. 5673 - 5676
反应条件
1: With 18-crown-6 ether; potassium tert-butylate in dichloromethane
T=-78 - 20°C; 12 h;
2: With lithium aluminium tetrahydride in diethyl ether
T=0°C; 0.5 h; Product distribution / selectivity;
参考文献
UNIVERSITY OF WASHINGTON
Patent: US2008/249042 A1, 2008 ;
Location in patent: Page/Page column 2; 19; 22; Sheet 22/24 ;
反应条件
sodium methylate in methanol; N,N-dimethyl-formamide
参考文献
Manchand,P.S. et al.
Journal of the Chemical Society, 1965 , p. 2019 - 2026
502-70-5(2E,4E,6E,8E,10E,12E,14E)-2,6,11,15-四甲基-2,4,6,8,10,12,14-十六碳七烯二醛+
→
反应条件
sodium hydride in dichloromethane
Wittig reaction;
参考文献
Kildahl-Andersen, Geir; Anthonsen, Thorleif; Liaaen-Jensen, Synnove
Organic and Biomolecular Chemistry, 2007 , vol. 5, # 17 p. 2803 - 2811
