(S)-(+)-2-辛醇合成路线 （共 200 条）
反应条件
ethanol; silver(l) oxide
参考文献
Journal of the Chemical Society, , p. 1236,1241
反应条件
sulfuric acid in tetrahydrofuran 19 h; Heating;
参考文献
Sakaguchi, Kazuhiko; Higashino, Masato; Ohfune, Yasufumi
Tetrahedron, 2003 , vol. 59, # 34 p. 6647 - 6658
反应条件
[(C4Ph4COHOCC4Ph4)(μ-H)][(CO)4Ru2]; Novozym(R) 435; 2,4-dimethylpentan-3-one in toluene T=70°C; P=142.511 Torr; 40 h; Title compound not separated from byproducts;
参考文献
Tetrahedron Asymmetry, , vol. 16, # 9 p. 1603 - 1610
反应条件
1: With (-)-(S)-[2-(2-methoxynaphthalen-1yl)phenyl]diphenylphosphine; trichlorosilane; bis(η3-allyl-μ-chloropalladium(II)) T=40°C; 24 h; 2: With potassium fluoride; potassium hydrogencarbonate in tetrahydrofuran; methanol T=20°C; 0.333333 h; 3: With dihydrogen peroxide in tetrahydrofuran; methanol T=20°C; 12 h; Title compound not separated from byproducts;
参考文献
Chemistry - A European Journal, , vol. 13, # 4 p. 1117 - 1128
反应条件
(1S,2R)-(-)-2-(N,N-di-n-butylamino)-1-phenylpropan-1-ol in hexane 1.) r.t., 20 min; 2.) 0 deg C, 16 h;
参考文献
Soai, Kenso; Yokoyama, Shuji; Ebihara, Katsumi; Hayasaka, Tomoiki
Journal of the Chemical Society, Chemical Communications, 1987 , # 22 p. 1690 - 1691
反应条件
immobilized lipase from Candida antarctica (Novozyme SP 435); 1-n-butyl-3-methylimidazolium bistrifluoromethylsulfonylamide T=60°C; P=75007.5 Torr; 65.5 h;
参考文献
Advanced Synthesis and Catalysis, , vol. 345, # 11 p. 1221 - 1228
反应条件
1: 1.) i-BuMgBr, Cp2TiCl2 2: 91 percent / Ti(Oi-Pr)4, L(+)DET 3: 80 percent / CrO3, pyridine 4: diethyl ether / -78 - 0 °C 5: 85 percent / AlH3 / diethyl ether 6: H2SO4 / methanol / 0.5 h / -10 - 0 °C 7: H2 View Scheme
参考文献
Journal of Organic Chemistry, , vol. 51, # 24 p. 4728 - 4731
反应条件
1: 90 percent / Amberlyst A-26 NO3(1-) form / toluene / 3 h / Heating 2: H2 / Pd/C / methanol View Scheme
参考文献
Tetrahedron Letters, , vol. 26, # 28 p. 3369 - 3372
反应条件
PPh3 gold(I) chloro complex; silver trifluoromethanesulfonate in ethanol; benzene T=20°C;
参考文献
Tetrahedron Letters, , vol. 49, # 49 p. 7046 - 7049
反应条件
lithium aluminium tetrahydride; diethyl ether
参考文献
Journal of the American Chemical Society, , vol. 80, p. 1611
Collection of Czechoslovak Chemical Communications, , vol. 23, p. 2081,2088
