反应条件
sulfur in acetone Schlenk technique (N2): suspn. of Fe6S6(PEt3)4Cl2, sulfur and {(Ph3P)2N}Cl in acetone stirred (overnight), brown solid filtered (filtrate contained Et3PS and slight amount of Et3PO); washed (acetone), treated with acetonitrile, filtered, ether added to filtrate, -20 ° C (overnight), filtered, residue from MeCN treatment taken up in DMF, S removed, ether added (filtrate), -20 °C (overnight), 31P NMR, UV/Vis;
参考文献
Inorganic Chemistry, , vol. 27, p. 2339 - 2347
