in tetrahydrofuran
byproducts: (CuCl)(n); under N2; soln. of CuCl2 in THF at 25°C mixed with equimolar amt. of Ti complex in THF; stirred at 25°C for 2 h; filtered through Kieselgur; volatiles removed in vac.; sepd. by chromy.(Kieselgel, -20°C, n-pentane);
参考文献
Frosch; Back; Koehler; Lang
Journal of Organometallic Chemistry, 2000 , vol. 601, # 2 p. 226 - 232
in tetrahydrofuran
byproducts: (CH3)3SiCCCCSi(CH3)3; under N2; addn. of equimolar amt. of HgCl2 to Ti complex in THF at 25°C, stirring for 2 h at this temp.;
参考文献
Frosch; Del Villar; Lang
Journal of Organometallic Chemistry, 2000 , vol. 602, # 1-2 p. 91 - 96
