potassium carbonate; triphenylphosphine; [Ru(II)(η6-benzene)(μ-Cl)Cl]2 in 1-methyl-pyrrolidin-2-one T=120°C; 20 h;

iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane; 4,4'-di-tert-butyl-2,2'-dipyridyl in tetrahydrofuran; chlorobenzene T=0°C; 0.0833333 h; Inert atmosphere;

lithium in tetrahydrofuran T=25°C; 24 h; var. temp., var. reaction times, other solvent; Product distribution;

iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane; 4,4'-di-tert-butyl-2,2'-dipyridyl in tetrahydrofuran; chlorobenzene T=0°C; 0.0833333 h; Inert atmosphere;

1: iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane; 4,4'-di-tert-butyl-2,2'-dipyridyl / tetrahydrofuran; chlorobenzene / 0.08 h / 0 °C / Inert atmosphere 2: iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane; 4,4'-di-tert-butyl-2,2'-dipyridyl / tetrahydrofuran; chlorobenzene / 0.08 h / 0 °C / Inert atmosphere View Scheme

1: iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane; 4,4'-di-tert-butyl-2,2'-dipyridyl / tetrahydrofuran; chlorobenzene / 0.08 h / 0 °C / Inert atmosphere 2: iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane; 4,4'-di-tert-butyl-2,2'-dipyridyl / tetrahydrofuran; chlorobenzene / 0.08 h / 0 °C / Inert atmosphere View Scheme

nickel monoaluminide in cyclohexane

nickel monoaluminide in cyclohexane