1,1,2-三氟-1,3-丁二烯合成路线 （共 7 条）
反应条件
potassium hydroxide; tetrabutylammomium bromide in xylene
T=60°C; 5 h;
参考文献
The University of Rochester
Patent: US4902835 A1, 1990 ;
反应条件
lithium chloride in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8)
T=20°C; P=2660.18 Torr; 0.5 h; Inert atmosphere;
参考文献
Ohashi, Masato; Kamura, Ryohei; Doi, Ryohei; Ogoshi, Sensuke
Chemistry Letters, 2013 , vol. 42, # 8 p. 933 - 935
反应条件
tributyl-amine
T=180°C;
参考文献
Tarrant et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 2783,2787
反应条件
potassium hydroxide; mineral oil
T=95°C;
参考文献
Park et al.
Journal of the American Chemical Society, 1956 , vol. 78, p. 59,60
反应条件
isopropyl alcohol; zinc(II) chloride; zinc
参考文献
Tarrant; Lilyquist
Journal of the American Chemical Society, 1955 , vol. 77, p. 3640
反应条件
1: in tetrahydrofuran
T=-40°C; 0.166667 h;
2: With methyllithium in tetrahydrofuran
T=-40°C; 2 h;
参考文献
Konno, Tsutomu; Takano, Shinya; Takahashi, Yoshikazu; Konishi, Hideaki; Tanaka, Yusuke; Ishihara, Takashi
Synthesis, 2011 , # 1 p. 33 - 44
参考文献
Geyer et al.
Journal of the Chemical Society, 1957 , p. 4472,4479
