苯-1,3,5-三基三(三甲基硅烷)合成路线 （共 18 条）
反应条件
1.1: 90 percent / ICl / CH2Cl2 / 0 °C 2.1: BuLi / toluene; hexane / 72 h / 20 °C 2.2: toluene; hexane / 24 h View Scheme
参考文献
Beinhoff, Matthias; Karakaya, Birol; Schlueter, A. Dieter
Synthesis, 2003 , # 1 p. 79 - 90
反应条件
iodine cloride in dichloromethane T=0 - 20°C;
参考文献
Banno, Motonori; Yamaguchi, Tomoko; Nagai, Kanji; Kaiser, Christian; Hecht, Stefan; Yashima, Eiji
Journal of the American Chemical Society, 2012 , vol. 134, # 20 p. 8718 - 8728
反应条件
1: 77 percent / AlCl3 / CS2 / 1 h / 0 °C 2: 33 percent / Ca(OCl)2, K2CO3, KOH / H2O / 7.5 h / 110 °C 3: SOCl2, CaCO3 / benzene; dimethylformamide / 2 h / Ambient temperature 4: 36 percent / Et3N / benzene View Scheme
参考文献
Journal of Medicinal Chemistry, , vol. 33, # 5 p. 1430 - 1437
反应条件
1: 77 percent / AlCl3 / CS2 / 1 h / 0 °C 2: 33 percent / Ca(OCl)2, K2CO3, KOH / H2O / 7.5 h / 110 °C View Scheme
参考文献
Yamakawa, Takeru; Kagechika, Hiroyuki; Kawachi, Emiko; Hashimoto, Yuichi; Shudo, Koichi
Journal of Medicinal Chemistry, 1990 , vol. 33, # 5 p. 1430 - 1437
反应条件
1: 77 percent / AlCl3 / CS2 / 1 h / 0 °C 2: 66 percent / 1 N NaOH / tetrahydrofuran View Scheme
参考文献
Yamakawa, Takeru; Kagechika, Hiroyuki; Kawachi, Emiko; Hashimoto, Yuichi; Shudo, Koichi
Journal of Medicinal Chemistry, 1990 , vol. 33, # 5 p. 1430 - 1437
反应条件
1: 59 percent / fuming HNO3/Ac2O / 2 h / -10 °C 2: 96 percent / H2 / 10percent Pd/C / benzene View Scheme
参考文献
Journal of Medicinal Chemistry, , vol. 33, # 5 p. 1430 - 1437
反应条件
1: 77 percent / AlCl3 / CS2 / 1 h / 0 °C 2: 33 percent / Ca(OCl)2, K2CO3, KOH / H2O / 7.5 h / 110 °C 3: SOCl2, CaCO3 / benzene; dimethylformamide / 2 h / Ambient temperature 4: 36 percent / Et3N / benzene 5: 66 percent / aq. NaOH/EtOH View Scheme
参考文献
Journal of Medicinal Chemistry, , vol. 33, # 5 p. 1430 - 1437
反应条件
sodium; (DMSC)TiCl2 in benzene-d6
T=80°C; cyclotrimerization; 5 h; Product distribution; Further Variations:Catalysts;
参考文献
Ozerov, Oleg V.; Ladipo, Folami T.; Patrick, Brian O.
Journal of the American Chemical Society, 1999 , vol. 121, # 34 p. 7941 - 7942
反应条件
sodium hydroxide; diphenyl-(o-hydroxyphenyl)-phosphine; PdCl(π-C3H5)2 in tetrahydrofuran
T=100°C; Substitution; Silylation; 24 h;
参考文献
Shirakawa; Kurahashi; Yoshida; Hiyama
Chemical Communications, 2000 , # 19 p. 1895 - 1896
反应条件
n-butyllithium in hexane
T=-80°C; 2 h;
参考文献
Mechtler, Christian; Zirngast, Michaela; Gaderbauer, Walter; Wallner, Andreas; Baumgartner, Judith; Marschner, Christoph
Journal of Organometallic Chemistry, 2006 , vol. 691, # 1-2 p. 150 - 158
