in tetrachloromethane heating 1 g Nb2O5 and 4 ml CCl4 in sealed tube to 270-300°C for 5-10 h, cooling down;; removal of excess CCl4 by vac. distn., sublimation of NbCl5 in vac.;;
参考文献
Schaefer, H.; Goeser, C.; Bayer, L.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1951 , vol. 265, p. 258 - 272
in neat (no solvent) carbon atoms formed in a carbon arc, reaction at -196°C with CCl4; mechanism discussed;;
参考文献
Skell, P. S.; Harris, R. F.
Journal of the American Chemical Society, 1965 , vol. 87, p. 5807 - 5808
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Gmelin Handbook: C: MVol.D2, 4.1.2.7.7.9, page 237 - 238
