in acetonitrile Kinetics; Under Ar, CCl4 is added to soln. of (C5H5)Fe(CO)2(CH2CHCH2), reaction is completed in 1-2 days at 25°C, further products.; Monitored by UV, analyzed by gas chromy.;
W(CO)6 T=140°C; 1 h; chain termination in the telomerization of title compound; Product distributionMechanism;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 36, # 12 p. 2641 - 2643
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 12 p. 2844 - 2847
in neat (no solvent) under exclusion of air moisture; Pr6O11 heated and held in CCl4 vapor at950 K for 11 h; according to V. F. Goryushkin, A. I. Poshevneva, V. S. Emel'yanov, USSR Inventor's Certificate No.1675209, Byull. Izobret., No. 33 (1991); elem. anal.;
参考文献
Goryushkina; Monaenkova; Popova; Tiflova
Russian Journal of Physical Chemistry A, 2006 , vol. 80, # 5 p. 697 - 701
Frank et al.
Industrial and Engineering Chemistry, 1949 , vol. 41, p. 2062
Full Text Show Details
Du Pont de Nemours and Co.
Patent: US2378048 , 1944 ;
aluminium trichloride in neat (no solvent) reaction of gaseous CO in the presence of AlCl3 at 100°C and 50 Torr; mechanism discussed;; yield depending on temp. and pressure;;
参考文献
Frank, C. F.; Hallowell, A. T.; Theobald, C. W.; Vaala, G. T.
Industrial and Engineering Chemistry, 1949 , vol. 41, p. 2061 - 2062
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Gmelin Handbook: C: MVol.D2, 4.1.2.7.8.5, page 244 - 244
aluminium trichloride; copper(l) chloride; iron(II) chloride T=120°C; P=75005.9 Torr; 5 h; other polychloroalkanes; other metallic salt mixtures; var. pressure, temp. and time of reaction; Mechanism;
参考文献
Monflier, Eric; Mortreux, Andre; Petit, Francis; Lecolier, Serge
Journal of the Chemical Society, Chemical Communications, 1992 , # 5 p. 439 - 441
