(E)-3,7-二甲基-2,6-辛二烯腈合成路线 （共 17 条）
反应条件
3 A molecular sieve; oxygen; copper(l) chloride in toluene T=80°C; P=760 Torr; 12 h;
参考文献
Maeda, Yasunari; Nishimura, Takahiro; Uemura, Sakae
Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 12 p. 2399 - 2403
反应条件
4-(N,N-dimethlyamino)pyridine; copper(l) iodide; ABNO; oxygen; 4,4'-di-tert-butyl-2,2'-dipyridyl in acetonitrile T=20°C; P=760.051 Torr; 15 h; Reagent/catalyst; Overall yield = 95 percent;
参考文献
ACS Catalysis, , vol. 3, # 7 p. 1652 - 1656
反应条件
2,3'-bipyridine; ammonium hydroxide; copper(l) iodide; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; oxygen in acetonitrile T=50°C; 24 h; Overall yield = 75 percent; Overall yield = 111.9 mg;
参考文献
Organic Letters, , vol. 15, # 8 p. 1850 - 1853
反应条件
sodium hydride in tetrahydrofuran 0 deg C, then Rt 1 h;
参考文献
Gebhard, R.; Courtin, J. M. L.; Shadid, J. B.; Haveren, J. van; Haeringen, C. J. van; Lugtenburg, J.
Recueil des Travaux Chimiques des Pays-Bas, 1989 , vol. 108, # 6 p. 207 - 214
反应条件
nickel sulphate; ammonium hydroxide; sodium hydroxide; dipotassium peroxodisulfate in water 6 h; Ambient temperature;
参考文献
Yamazaki, Shigakazu; Yamazaki, Yasuyuki
Chemistry Letters, 1990 , # 4 p. 571 - 574
反应条件
nickel sulphate; ammonium hydroxide; sodium hydroxide; dipotassium peroxodisulfate in water 6 h; Ambient temperature;
参考文献
Chemistry Letters, , # 4 p. 571 - 574
反应条件
1: 15 percent / aq. NH3, NiSO4-K2S2O8, NaOH / H2O / 6 h / Ambient temperature 2: 48 percent / aq. NH3, NiSO4-K2S2O8, NaOH / H2O / 6 h / Ambient temperature View Scheme
参考文献
Chemistry Letters, , # 4 p. 571 - 574
反应条件
1: 70 percent / diethyl ether / 3 h / 0 °C 2: 85 percent / NaH / tetrahydrofuran / 0 deg C, then Rt 1 h View Scheme
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 108, # 6 p. 207 - 214
反应条件
1: 1.) BuLi / 1.) THF, hexane, -60 deg C, 15 min; 2.) THF, hexane, -50 deg C, 1 h 2: 70 percent / diethyl ether / 3 h / 0 °C 3: 85 percent / NaH / tetrahydrofuran / 0 deg C, then Rt 1 h View Scheme
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 108, # 6 p. 207 - 214
反应条件
hydrogen; palladium on activated carbon in water T=50 - 81°C; P=3750.38 - 37503.8 Torr; 4.83333 - 6 h; Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2006/106141 A1, 2006 ;
Location in patent: Page/Page column 10-11 ;
