in water byproducts: H2; addn. of H2O to a suspension of NaBH4 and ammonium-salt in (C2H5)3N at -10°C (during 3h), removal of (C2H5)3N, addn. of petroleum ether and H2O;; isolation from the organic phase by distn.;;
参考文献
Gmelin Handbook: B: B-Verb.14, 3.8.1.2.1, page 94 - 97
Full Text Show Details
Borax & Chemical Corp.
Patent: GB952811 , 1964 ;
C., 1965 , p. 20-2169
in diethyl ether addn. of Li(BH4) in ether to the ether-soln. of the ammonium-salt (dried at 100°C in vac.) under N2 while stirring, refluxing for 1h;;
参考文献
Greenwood, N. N.; Morris, J. H.
Journal of the Chemical Society, 1960 , p. 2922 - 2927
Full Text View citing articles Show Details
Gmelin Handbook: B: B-Verb.14, 3.8.1.2.1, page 94 - 97
React. of starting materials (vac., 135-150°C, 46 h).; Sepn. of volatile materials by fractional condensation. Identification by combination of use of calibrated traps, quantitative IR anal. and GC/MS.;
