氯代氢三(三苯基膦)钌(II)甲苯加合物合成路线 （共 9 条）
反应条件
in methyl ethyl ketone=butan-2-one stirred (12 h); refluxed (16 h);
参考文献
Journal of Organometallic Chemistry, , vol. 312, p. C64 - C66
反应条件
in toluene byproducts: CH4; under Ar; one equivalent of each complex; refluxing toluene; recrystallization; IR, NMR;
参考文献
Nouveau Journal de Chimie, , vol. 7, p. 181 - 184
反应条件
1: N2 / tetrahydrofuran 2: triphenylphosphine / tetrahydrofuran View Scheme
参考文献
Cole-Hamilton, David J.; Wilkinson, Geoffrey
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 797 - 804
反应条件
in tert-butyl alcohol Ar-atmosphere; dissoln. of K in t-BuOH, filtration onto Ru-complex, stirring for several h (pptn.); filtration off of (RuH(OH)(PPh3)2(t-BuOH))2, pptn. on addn. of light petroleum; elem. anal.;
参考文献
Chaudret, Bruno N.; Cole-Hamilton, David J.; Nohr, Ronald S.; Wilkinson, Geoffrey
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 1546 - 1557
反应条件
in tetrahydrofuran Ar-atmosphere; stirring (16 h); evapn. to dryness, extn. into toluene, addn. of light petroleum, filtration, crystn. on standing;
参考文献
Chaudret, Bruno N.; Cole-Hamilton, David J.; Nohr, Ronald S.; Wilkinson, Geoffrey
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 1546 - 1557
反应条件
in methanol; diethyl ether Ar-atmosphere; pptn. on stirring of Ru-complex and NaOCH3 (2 vol.percent MeOH,0°C, 3 h); collection, drying (vac.), recrystn. (toluene/light petroleum);
参考文献
Chaudret, Bruno N.; Cole-Hamilton, David J.; Nohr, Ronald S.; Wilkinson, Geoffrey
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 1546 - 1557
反应条件
2-pyridyl methyl ketone in chloroform byproducts: CH2Cl2; 4 mol percent MeC(O)C5H4N;
参考文献
Vriends, Rob. C. J.; Koten, Gerard van; Vrieze, Kees
Inorganica Chimica Acta, 1978 , vol. 26, p. L29 - L31
反应条件
in tetrahydrofuran byproducts: Ph3PO, PPh3; (Ar); standard Schlenk technique; Ru complex was treated with ligand (1 equiv.) in THF; NMR monitoring;
参考文献
Dahlenburg, Lutz; Kuehnlein, Christian
Journal of Organometallic Chemistry, 2005 , vol. 690, # 1 p. 1 - 13
反应条件
in toluene
T=20°C; 24 h; Inert atmosphereSchlenk techniqueGlovebox;
参考文献
Wang, Tongen; Pranckevicius, Conor; Lund, Clinton L.; Sgro, Michael J.; Stephan, Douglas W.
Organometallics, 2013 , vol. 32, # 7 p. 2168 - 2177
