in not given byproducts: Me2NH; N2-atmosphere; 2 equiv. i-PrOH, stirring (room temp., <= 30 min); in CH2Cl2 or pentane or Et2O (not specified); product mixt. not isolated, detd. by (11)B-NMR spectroscopy;
参考文献
Journal of Organometallic Chemistry, , vol. 489, # 1-2 p. 51 - 62
in not given byproducts: Me2NH; N2-atmosphere; 2 equiv. i-PrOH, stirring (room temp., <= 30 min); in CH2Cl2 or pentane or Et2O (not specified); product mixt. not isolated, detd. by (11)B-NMR spectroscopy;
参考文献
Journal of Organometallic Chemistry, , vol. 489, # 1-2 p. 51 - 62
in neat (no solvent) Me3SiCl, Me3SiOSiMe3 and 2-propanol stirred for 30 min, boric acid added and stirred for 3 h; soln. filtered and concd., mixt. analysed by using combined gas chromatograph-mass spectroscopy;
1: With N,N,N',N,-tetramethylethylenediamine; sec.-butyllithium in tetrahydrofuran; cyclohexane T=-78°C; 2 h; 2: With tri-isopropoxy-borane in tetrahydrofuran; cyclohexane T=-78°C; 0.666667 h;
