1: 93 percent / dimethylformamide / 3 h / Ambient temperature 2: 90 percent / piperidine, DBU / acetonitrile / 5 h / Ambient temperature View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 56, # 3 p. 949 - 950
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反应条件
in toluene soln. of Ti complex treated with PhCH2Br, refluxed with stirring under N2 for 4.5 h; evapn. to dryness (rotatory evaporator) upon cooling, extn. (hexanes), filtration (insol. Cp2TiBr2), evapn. of the filtrate;
H4Mo2S12(2-)*2H(1+)*2H3N in benzene 48 h; Heatingacetonitrile was also used as a solvent, sulfide/disulfide ratio was investigated by variable reaction time and solvent; Product distribution;
