三甲基-(2-苯基-环己-1-烯基氧基)-硅烷合成路线 （共 11 条）
反应条件
tin(IV) chloride; (R,R)-(-)-2-benzyloxy-1,2-bis[3,5-bis(trifluoromethyl)phenyl]ethanol in hexane; dichloromethane T=-78°C; 1 h;
参考文献
Ishihara, Kazuaki; Nakashima, Daisuke; Hiraiwa, Yukihiro; Yamamoto, Hisashi
Journal of the American Chemical Society, 2003 , vol. 125, # 1 p. 24 - 25
反应条件
(R)-binaphthol-SnCl4 in dichloromethane T=-100°C; 0.0833333 h; enantioselective protonation silyl enol ethers and ketene bis(trialkylsilyl) acetals; var. solv, temp.;
参考文献
Ishihara; Nakamura; Kaneeda; Yamamoto
Journal of the American Chemical Society, 1996 , vol. 118, # 50 p. 12854 - 12855
反应条件
(S)-HOP; isopropyl alcohol; scandium tris(trifluoromethanesulfonate) in dichloromethane T=20°C; 12 h; Inert atmosphere;
参考文献
Cheon, Cheol Hong; Imahori, Tatsushi; Yamamoto, Hisashi
Chemical Communications, 2010 , vol. 46, # 37 p. 6980 - 6982
反应条件
1: 2-phenyl-cyclohexanone With lithium diisopropyl amide in tetrahydrofuran
T=-78 - 20°C; Inert atmosphere;
2: chloro-trimethyl-silane in tetrahydrofuran
T=20°C; 2 h; Inert atmosphere;
参考文献
Cheon, Cheol Hong; Kanno, Osamu; Toste, F. Dean
Journal of the American Chemical Society, 2011 , vol. 133, # 34 p. 13248 - 13251
反应条件
triethylamine in N,N-dimethyl-formamide
T=130°C; enolization; silylation; 90 h; Title compound not separated from byproducts.;
参考文献
Nakamura, Shingo; Kaneeda, Masanobu; Ishihara, Kazuaki; Yamamoto, Hisashi
Journal of the American Chemical Society, 2000 , vol. 122, # 34 p. 8120 - 8130
反应条件
1: tris-(dibenzylideneacetone)dipalladium(0); tri-n-butyltin fluoride; triethylamine; [(t-Bu)3PH]BF4 / benzene / 24 h / 80 °C / Inert atmosphere
2: pyridine; sodium iodide / hexane; acetonitrile / 20 h / 20 °C
View Scheme
参考文献
Beck, Elizabeth M.; Hyde, Alan M.; Jacobsen, Eric N.
Organic Letters, 2011 , vol. 13, # 16 p. 4260 - 4263
反应条件
1: tris-(dibenzylideneacetone)dipalladium(0); tri-n-butyltin fluoride; triethylamine; [(t-Bu)3PH]BF4 / benzene / 24 h / 80 °C / Inert atmosphere
2: pyridine; sodium iodide / hexane; acetonitrile / 20 h / 20 °C
View Scheme
参考文献
Beck, Elizabeth M.; Hyde, Alan M.; Jacobsen, Eric N.
Organic Letters, 2011 , vol. 13, # 16 p. 4260 - 4263
反应条件
N,N,N',N,-tetramethylethylenediamine; zinc in diethyl ether
参考文献
Rubottom,G.M. et al.
Synthetic Communications, 1977 , vol. 7, p. 327 - 332
反应条件
2,4,6-trimethyl-pyridine; 2,3-dicyano-5,6-dichloro-p-benzoquinone in benzene
6 h;
参考文献
Bockman, T. Michael; Shukla; Kochi, Jay K.
Journal of the Chemical Society. Perkin Transactions 2, 1996 , vol. 8, p. 1623 - 1632
反应条件
in dichloromethane
Irradiation; Quantum yieldProduct distributionMechanism;
参考文献
Bockman, T. Michael; Kochi, Jay K.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1996 , # 8 p. 1633 - 1644
