N,N'-二苯基联苯二胺合成路线 （共 29 条）
反应条件
1: in 1-methyl-pyrrolidin-2-one; toluene T=20°C; 0.25 h; 2: With sodium t-butanolate in 1-methyl-pyrrolidin-2-one; toluene 0.166667 h; 3: With tris-(dibenzylideneacetone)dipalladium(0); 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in 1-methyl-pyrrolidin-2-one; toluene T=20 - 60°C; 24.5 h; Product distribution / selectivity;
参考文献
LANXESS DEUTSCHLAND GMBH
Patent: WO2006/108544 A1, 2006 ;
Location in patent: Page/Page column 10 ;
反应条件
sodium t-butanolate; Ni(0)*2IPr in 1,4-dioxane T=100°C;
参考文献
Kuhl, Sebastien; Fort, Yves; Schneider, Raphael
Journal of Organometallic Chemistry, 2005 , vol. 690, # 24-25 p. 6169 - 6177
反应条件
1: HN(SiMe3)(Ph) With n-butyl-magnesium bromide in anhydrous butyl ether T=0 - 100°C; 1 h; Inert atmosphere; 2: 4,4'-dibromo biphenyl With lithium bromide; iron(II) chloride in anhydrous butyl ether T=140°C; 24 h; Inert atmosphere;
参考文献
Hatakeyama, Takuji; Imayoshi, Ryuji; Yoshimoto, Yuya; Ghorai, Sujit K.; Jin, Masayoshi; Takaya, Hikaru; Norisuye, Kazuhiro; Sohrin, Yoshiki; Nakamura, Masaharu
Journal of the American Chemical Society, 2012 , vol. 134, # 50 p. 20262 - 20265
反应条件
pyridine; NOBF4 in acetonitrile Mechanism;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 19, # 4 p. 662 - 666
Zhurnal Organicheskoi Khimii, , vol. 19, # 4 p. 751 - 756
反应条件
sulfuric acid; acetic acid
参考文献
Chemische Berichte, , vol. 46, p. 3297,3300
Chemische Berichte, , vol. 52, p. 889
Bulletin de la Societe Chimique de France, , vol. <4> 15, p. 194
反应条件
sulfuric acid T=-20°C;
参考文献
Chemische Berichte, , vol. 46, p. 3306
反应条件
1.1: triethylamine / cyclohexane / 2 h / 5 °C / |Inert atmosphere 1.2: 18 h / 5 °C / |Inert atmosphere 2.1: n-butyl-magnesium bromide / anhydrous butyl ether / 1 h / 0 - 100 °C / |Inert atmosphere 2.2: 24 h / 140 °C / |Inert atmosphere View Scheme
参考文献
Journal of the American Chemical Society, , vol. 134, # 50 p. 20262 - 20265
反应条件
sulfuric acid T=-16°C;
参考文献
Chemische Berichte, , vol. 46, p. 3306
反应条件
sulfuric acid; acetic acid Reduktion der entstandenen Loesung mit Zinkstaub;
参考文献
Bulletin de la Societe Chimique de France, , vol. <4>15, p. 512
反应条件
HY zeolite in dichloromethane T=20°C; Product distribution; Further Variations:ReagentsTemperatures;
参考文献
New Journal of Chemistry, , vol. 28, # 7 p. 807 - 814
