4-甲基-3-环己烯-1-酮合成路线 (共 33 条)
反应条件
copper(II) sulfate in methanol; water 2 h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Boucher, Jean-Luc; Stella, Lucien
Tetrahedron, 1985 , vol. 41, # 5 p. 875 - 887
参考文献
Dauben,W.G. et al.
Journal of the American Chemical Society, 1973 , vol. 95, # 2 p. 468 - 471
反应条件
disodium hydrogenphosphate; sodium amalgam; toluene-4-sulfonic acid 1.) methanol, 2.5 h, 2.) ethanol, water, 20.5 h, reflux; Yield given. Multistep reaction;
参考文献
Kinney, William A.; Crouse, Gary D.; Paquette, Leo A.
Journal of Organic Chemistry, 1983 , vol. 48, # 25 p. 4986 - 5000
反应条件
oxalic acid Multistep reaction;
参考文献
Buchmann et al.
Tetrahedron, 1984 , vol. 40, p. 3393
反应条件
disodium hydrogenphosphate; sodium amalgam; toluene-4-sulfonic acid 1.) methanol, room temp., 30 min, 2.) ethanol, reflux, 20 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Paquette, Leo A.; Kinney, William A.
Tetrahedron Letters, 1982 , vol. 23, # 2 p. 131 - 134
反应条件
ethanol; ammonia; sodium Kochen des gebildeten 4-Methoxy-1-methyl-cyclohexadiens-(1.4) mit wss. H2SO4 oder wss. NaHSO3-Loesung;
参考文献
Birch
Journal of the Chemical Society, 1946 , p. 593,597
Journal of the Chemical Society, 1947 , p. 1642,1644, 1648
反应条件
1) Birch reduction, 2) acid hydrolysis; Multistep reaction;
参考文献
Engel, Paul S.; Robertson, Donald M.; Scholz, John N.; Shine, Henry J.
Journal of Organic Chemistry, 1992 , vol. 57, # 23 p. 6178 - 6187
反应条件
Yield given. Multistep reaction;
参考文献
Engel, Paul S.; Robertson, Donald M.; Scholz, John N.; Shine, Henry J.
Journal of Organic Chemistry, 1992 , vol. 57, # 23 p. 6178 - 6187
参考文献
Birch
Journal and Proceedings of the Royal Society of New South Wales, 1949 , vol. 83, p. 245,248
反应条件
Yield given. Multistep reaction;
参考文献
Boucher, Jean-Luc; Stella, Lucien
Tetrahedron, 1988 , vol. 44, # 12 p. 3607 - 3616