in dimethyl sulfoxide
T=25°C; kinetic of reactions of cyclic secondary amines (pyrrolidine, piperidine) with 2,4-dinitro-1-naphthyl ethyl ether in DMSO; stage II kinetics (with piperidine); difference between the piperidine and pyrrolidine systems; Rate constant;
参考文献
Bunnett, Joseph F.; Sekiguchi, Shizen; Smith, Lewis A.
Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4865 - 4871
in dimethyl sulfoxide
T=25°C; kinetic of reactions of cyclic secondary amines (pyrrolidine, piperidine) with 2,4-dinitro-1-naphthyl ethyl ether in DMSO; stage I and II kinetics (with piperidine); reaction in the presence of piperidinium and N,N-dimethyl piperidinium chlorides; Rate constantMechanism;
参考文献
Bunnett, Joseph F.; Sekiguchi, Shizen; Smith, Lewis A.
Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4865 - 4871