1-氯-2,3,4,6-四氟苯合成路线 （共 7 条）
反应条件
para-dichlorobenzene; 1,2-dichloro-3,4,5,6-tetrafluorobenzene; phosphorous acid trisdiethylamide in hexane
T=20°C; Reduction; silyldehalogenation; 168 h; Title compound not separated from byproducts;
参考文献
Bardin
Russian Chemical Bulletin, 1997 , vol. 46, # 4 p. 780 - 785
反应条件
copper(l) chloride in N,N-dimethyl-formamide
Heating;
参考文献
Burdon,J. et al.
Tetrahedron, 1966 , vol. 22, p. 2541 - 2549
反应条件
1: (i) Br2, AlBr3, SO3/H2SO4, (ii) Zn, AcOH
2: CuCl / dimethylformamide / Heating
View Scheme
参考文献
Burdon,J. et al.
Tetrahedron, 1966 , vol. 22, p. 2541 - 2549
反应条件
1: aq. H2SO4
2: (heating)
View Scheme
参考文献
Vlasov,V.M. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1967 , vol. 37, # 1 p. 171 - 176,156 - 160
反应条件
1: KF / 280 - 285 °C
2: aq. H2SO4
3: (heating)
View Scheme
参考文献
Vlasov,V.M. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1967 , vol. 37, # 1 p. 171 - 176,156 - 160
反应条件
(i) Mg, THF, (ii) aq. H2SO4; Multistep reaction;
参考文献
Burdon,J. et al.
Tetrahedron, 1966 , vol. 22, p. 2541 - 2549
参考文献
Vlasov,V.M. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1967 , vol. 37, # 1 p. 171 - 176,156 - 160
