3-甲基-6-庚烯-1-炔-3-醇合成路线 （共 6 条）
反应条件
in tetrahydrofuran; xylene
T=0 - 23°C;
参考文献
PRESIDENT AND FELLOWS OF HARVARD COLLEGE
Patent: WO2006/102097 A2, 2006 ;
Location in patent: Page/Page column 31/33 ;
反应条件
potassium carbonate in methanol
T=20°C;
参考文献
Gronnier, Colombe; Boissonnat, Guillaume; Gagosz, Fabien
Organic Letters, 2013 , vol. 15, # 16 p. 4234 - 4237
反应条件
in tetrahydrofuran; diethyl ether
T=20°C; 3 h;
参考文献
Anjum, Shazia; Marco-Contelles, Jose
Tetrahedron, 2005 , vol. 61, # 20 p. 4793 - 4803
反应条件
1.1: n-butyllithium / hexane; tetrahydrofuran / 0.5 h / -78 °C
1.2: -78 °C
2.1: potassium carbonate / methanol / 20 °C
View Scheme
参考文献
Gronnier, Colombe; Boissonnat, Guillaume; Gagosz, Fabien
Organic Letters, 2013 , vol. 15, # 16 p. 4234 - 4237
反应条件
caesium carbonate in water; dimethyl sulfoxide
T=60°C; 8 h; Inert atmosphereGreen chemistry;
参考文献
Sum, Yin Ngai; Yu, Dingyi; Zhang, Yugen
Green Chemistry, 2013 , vol. 15, # 10 p. 2718 - 2721
反应条件
potassium hydroxide; diethyl ether; ethanol
参考文献
Nasarow et al.
Doklady Akademii Nauk SSSR, 1957 , vol. 114, p. 796,798
Doklady Chemistry, 112-117<1957>579,581
