acetate-phosphate buffer T=25°C; pH 3.0; var. pH; var. temps.; ΔS(excit.), ΔH(excit.), ΔG(excit.); Rate constantMechanismThermodynamic data;
参考文献
Cano, Maria Constanza Soriano; Sanchez, Juan Vera
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 3 p. 427 - 430
in water aq. soln. of NaOH was added to mixt. of aq. soln. of acid/KNO3 and aq. soln. of Me3SnCl/KNO3 (ascorbic acid/Me2SnCl2 = 1/1) at 298 K under N2;
参考文献
Nath, Mala; Jairath, Ruchi; Eng, George; Song, Xueqing; Kumar, Ashok
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2005 , vol. 61, # 1-2 p. 77 - 86
Chauhan, R. P. S.; Singh, Uttam Bahadur
Journal of the Indian Chemical Society, 1995 , vol. 72, # 5 p. 355 - 356
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反应条件
hydrogenchloride in water T=25°C; pH=1.3; Kinetics; pH-valueReagent/catalystConcentrationTemperature;
参考文献
Cox, Brian G.; Jedral, Wojciech; Palou, Josefina
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 733 - 740
Cu(II) perchlorate in water Kinetics; byproducts: H2O; reaction rates in aq. solns. estimated from absorbance changes at 382 nm; ionic strength regulated by addn. of LiClO4; 25°C; HOAc-OAc(1-)buffers;
参考文献
Ghosh, S. K.; Gould, E. S.
Inorganic Chemistry, 1989 , vol. 28, p. 1948 - 1951
dihydrogen peroxide; copper(II) sulfate in water degradation of ascorbic acid in H2O2 and cupric ion solutions, oxidation with different oxygen sources, possible oxidation products, effect of cupric ion, GC/MS study; Product distribution;
参考文献
Deutsch, John C.; Santhosh-Kumar; Hassell, Kathryn L.; Kolhouse, J. Fred
Analytical Chemistry, 1994 , vol. 66, # 3 p. 345 - 350
