1: iodine; silver(l) oxide / tetrahydrofuran; water / 2 h / 20 °C 2: trifluoroacetic acid / tetrahydrofuran; water / |Reflux 3: tri-ruthenium(0)dodecacarbonyl; 1,3-bis-(diphenylphosphino)propane / toluene; N,N-dimethyl acetamide / 48 h / 130 °C / |Sealed tube; |Inert atmosphere 4: tetrabutylammonium dioxovanadium(V)-dipicolinate; sodium sulfite / benzene / 96 h / 180 °C / |Sealed tube 5: carbon / benzene / 72 h / 80 °C / 760.05 Torr / |Sealed tube; |Darkness View Scheme

iodosylbenzene; Fe(III)prorphyrinate (SbF-)3 salt in various solvent(s) Mechanism;

ammonia; sodium; potassium hydroxide in diethyl ether; ethanol T=-78°C; 5.5 h; Inert atmosphere;

white sand; calcium; tert-butyl alcohol in ethylenediamine T=0°C; 24 h; Yield given. Yields of byproduct given;

in N-dodecane T=150°C;

sodium amide

ammonia; lithium; tert-butyl alcohol in tetrahydrofuran Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

und fluessiger NH3;

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