1-苯基-1,3-丙二醇合成路线 （共 84 条）
反应条件
carbonyl-bis(trifluoroacetato)bis(triphenylphosphino)ruthenium(II); 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in toluene T=175°C; 17 h; vacuum-sealed tube; Product distribution / selectivity;
参考文献
WO2011/3029 A2, ;
Page/Page column 91 ;
反应条件
tributylphosphine in tetrahydrofuran 1 h; Ambient temperature;
参考文献
Ikemizu, Dai; Matsuyama, Ayako; Takemura, Kazunori; Mitsunobu, Oyo
Synlett, 1997 , vol. 1997, # 11 p. 1247 - 1248
反应条件
hydrogen; Pd catalyst in butan-1-ol T=100°C; other catalysts; Kinetics;
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 52, # 8 p. 2019 - 2027
反应条件
cobalt(II) chloride in acetonitrile T=80°C; 3 h;
参考文献
Iqbal, Javed; Srivastava, Rajiv Ranjan
Journal of Organic Chemistry, 1992 , vol. 57, # 7 p. 2001 - 2007
反应条件
cobalt(II) chloride in acetonitrile T=80°C; 3 h;
参考文献
Iqbal, Javed; Srivastava, Rajiv Ranjan
Journal of Organic Chemistry, 1992 , vol. 57, # 7 p. 2001 - 2007
反应条件
carbonyl-bis(trifluoroacetato)bis(triphenylphosphino)ruthenium(II); 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in toluene T=175°C; 17 h; vacuum-sealed tube; Product distribution / selectivity;
参考文献
WO2011/3029 A2, ;
Page/Page column 91 ;
反应条件
1: 70 percent / pyridine / CH2Cl2 2: 77 percent / hydrazine hydrate / CH2Cl2 / 2 h 3: 60 percent / Na2SO4 / CH2Cl2 / 2 h 4: CH2Cl2 / 48 h 5: 26 percent / benzene; various solvent(s) / 72 h / 110 °C View Scheme
参考文献
Merkley, Nadine; Warkentin, John
Canadian Journal of Chemistry, 2002 , vol. 80, # 9 p. 1187 - 1195
反应条件
FeCl3·6H2O in dichloromethane Friedel-Crafts Alkylation; 24 h; Reflux;
参考文献
De Castro, Kathlia A.; Jungnam, Ko; Daejong, Park; Sungdae, Park; Hakjune, Rhee
Organic Process Research and Development, 2007 , vol. 11, # 5 p. 918 - 921
反应条件
1.1: 95 percent / Et3N / CH2Cl2 / 0 h / -10 °C 2.1: O2; (-)-sparteine; 3 Angstroem sieves / Pd(OAc)2 / toluene / 36 h / 80 °C / 760 Torr 2.2: H2O / tetrahydrofuran / 65 °C 2.3: PPh3; DEAD; HCl (g) / diethyl ether / -10 - 0 °C View Scheme
参考文献
Ali, Iliyas Sayyed; Sudalai, Arumugam
Tetrahedron Letters, 2002 , vol. 43, # 31 p. 5435 - 5436
反应条件
1: With di-isopropyl azodicarboxylate; triphenylphosphine in toluene T=0°C; Mitsunobu Displacement; 0.25 h; Inert atmosphere; 2: With chloro-trimethyl-silane in toluene T=20°C; Mitsunobu Displacement; 2 h; Inert atmosphere; regioselective reaction;
参考文献
Organic and Biomolecular Chemistry, , vol. 11, # 36 p. 6195 - 6207
