4-羟基-2-甲基-1,3-环戊烷二酮合成路线 (共 9 条)
反应条件
ethyl acetate; platinum
Hydrogenation;
参考文献
Orchin; Butz
Journal of the American Chemical Society, 1943 , vol. 65, p. 2296,2298
反应条件
1: aqueous phosphoric acid
2: water containing ethanol; platinum
View Scheme
参考文献
Orchin; Butz
Journal of the American Chemical Society, 1943 , vol. 65, p. 2296,2298
反应条件
ethanol; platinum
Hydrogenation;
参考文献
Orchin; Butz
Journal of the American Chemical Society, 1943 , vol. 65, p. 2296,2298
反应条件
(i) aq. NaOH, (ii) (heating); Multistep reaction;
参考文献
Corbett,J.F.
Journal of the Chemical Society [Section] C: Organic, 1967 , vol. <C>, p. 2408 - 2410
反应条件
4-hydroxy-3-methoxy-2-methyl-cyclopent-2-enone of mp: 86 degree;
参考文献
Orchin; Butz
Journal of the American Chemical Society, 1943 , vol. 65, p. 2296,2298
反应条件
des Monohydrats.Hydrogenation;
参考文献
Orchin; Butz
Journal of the American Chemical Society, 1943 , vol. 65, p. 2296,2298
Full Text Show Details
Nasarow et al.
Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 1482,1492
J. Gen. Chem. USSR (Engl. Transl.), 1956 , vol. 26, p. 1667,1675
反应条件
4-hydroxy-3-methoxy-2-methyl-cyclopent-2-enone of mp: 168 degree;
参考文献
Orchin; Butz
Journal of the American Chemical Society, 1943 , vol. 65, p. 2296,2298
参考文献
Orchin; Butz
Journal of the American Chemical Society, 1943 , vol. 65, p. 2296,2298
反应条件
1: methanol / Heating
2: Al(OiPr)3, iPrOH
3: Zn, AcOH
View Scheme
参考文献
Asako; Hiraga; Miki
Chemical and Pharmaceutical Bulletin, 1973 , vol. 21, # 4 p. 697 - 702