2-氧代-N,2-二苯基-乙酰胺合成路线 （共 41 条）
反应条件
in benzene
1.) 40 h, 55 deg C, 2.) 10 d, 25 deg C.;
参考文献
Fisera, Lubor; Dandarova, Miloslava; Kovac, Jaroslav; Mesko, Peter; Krutosikova, Alzbeta
Collection of Czechoslovak Chemical Communications, 1981 , vol. 46, # 10 p. 2421 - 2427
反应条件
1: SO2Cl2, AIBN / CCl4 / 15 h / Heating
2: ethyl acetate
View Scheme
参考文献
Burger,K.; Eggersdorfer,M.
Liebigs Annalen der Chemie, 1979 , p. 1547 - 1553
反应条件
1.1: magnesium / tetrahydrofuran / 1 h / 20 °C
1.2: 1 h / -78 - -10 °C
2.1: sodium hydroxide; water / tetrahydrofuran / 6 h / |Reflux
3.1: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 3 h / 20 °C
4.1: pyridine / dichloromethane / 12 h / 20 °C
View Scheme
参考文献
Shirai, Tomohiko; Ito, Hajime; Yamamoto, Yasunori
Angewandte Chemie - International Edition, 2014 , vol. 53, # 10 p. 2658 - 2661
Angew. Chem., 2014 , vol. 126, # 10 p. 2696 - 2699,4
反应条件
1: sodium hydroxide; water / tetrahydrofuran / 6 h / |Reflux
2: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 3 h / 20 °C
3: pyridine / dichloromethane / 12 h / 20 °C
View Scheme
参考文献
Shirai, Tomohiko; Ito, Hajime; Yamamoto, Yasunori
Angewandte Chemie - International Edition, 2014 , vol. 53, # 10 p. 2658 - 2661
Angew. Chem., 2014 , vol. 126, # 10 p. 2696 - 2699,4
反应条件
oxygen in dichloromethane
Irradiation; Further byproducts given;
参考文献
Kato, Hiroshi; Tani, Kazue; Kurumisawa, Haruki; Tamura, Yoshiko
Chemistry Letters, 1980 , p. 717 - 720
反应条件
1: dichloromethane / 1 h / 20 °C
2: tetra(n-butyl)ammonium hydrogensulfate; sodium hydrogencarbonate / 1,4-dioxane / 12 h / Reflux
View Scheme
参考文献
Shao, Jun; Huang, Xiaomei; Wang, Siyuan; Liu, Bingxin; Xu, Bin
Tetrahedron, 2012 , vol. 68, # 2 p. 573 - 579
反应条件
1: |Microwave irradiation
2: 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; Ca(OCl)2
View Scheme
参考文献
Stella, Selvaraj; Chadha, Anju
Catalysis Today, 2012 , vol. 198, # 1 p. 345 - 352
反应条件
1: |Microwave irradiation
2: 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; Ca(OCl)2
View Scheme
参考文献
Stella, Selvaraj; Chadha, Anju
Catalysis Today, 2012 , vol. 198, # 1 p. 345 - 352
参考文献
Wislicenus; Erbe
Justus Liebigs Annalen der Chemie, 1920 , vol. 421, p. 148
反应条件
sulfuric acid
Hydrolysis;
参考文献
Borsche; Fritzsche
Chemische Berichte, 1926 , vol. 59, p. 274
