2-乙烯基-6,6-二甲基双环[3.1.1]庚-2-烯合成路线 （共 6 条）
反应条件
n-butyllithium; potassium tert-butylate; diisopropylamine in tetrahydrofuran
T=-50°C;
参考文献
Margot, Christian; Rizzolio, Michele; Schlosser, Manfred
Tetrahedron, 1990 , vol. 46, # 7 p. 2411 - 2424
反应条件
acetic acid in methanol
T=62.5°C;
参考文献
Giddings, Rodney M.; Jones-Parry, Richard; Owen, Rawson; Whittaker, David
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 1525 - 1528
反应条件
1: 80 percent / sodium hydroxide, benzyltriethylammonium chloride / hexane; H2O / 4 h
2: 72 percent / diisopropylamine, butyllithium, potassium tert-butoxide / tetrahydrofuran / -50 °C
View Scheme
参考文献
Margot, Christian; Rizzolio, Michele; Schlosser, Manfred
Tetrahedron, 1990 , vol. 46, # 7 p. 2411 - 2424
反应条件
potassium hydrogensulfate; hydroquinone
1.) ether, 2.) bath temp. 140 deg C; Yield given. Multistep reaction;
参考文献
Tamaru, Yoshinao; Yamada, Yoshimi; Kagotani, Masahiro; Ochiai, Hirofumi; Nakajo, Eiji; et al.
Journal of Organic Chemistry, 1983 , vol. 48, # 24 p. 4669 - 4681
反应条件
(i) THF, (ii) I2; Multistep reaction;
参考文献
Paquette,L.A. et al.
Tetrahedron Letters, 1976 , p. 4033 - 4036
反应条件
lithium aluminium tetrahydride; sodium acetate; acetic acid
Mechanism;
参考文献
Vyglazov, O. G.; Urbanovich, T. R.; Manukov, E. N.; Chuiko, V. A.; Udarov, B. G.
Journal of Organic Chemistry USSR (English Translation), 1989 , vol. 25, # 101 p. 1896 - 1900
Zhurnal Organicheskoi Khimii, 1989 , vol. 25, # 10 p. 2100 - 2104
