双环[4.1.0]-1,3,5-庚三烯合成路线 （共 28 条）
反应条件
potassium tert-butylate in dimethyl sulfoxide
1 h; Ambient temperature;
参考文献
Neidlein, Richard; Poignee, Volker
Chemische Berichte, 1988 , vol. 121, p. 1199 - 1200
反应条件
1: 1.) aq.NaOH, benzyldimethyl(2-hydroxyethyl)ammonium chloride / 1.) methylcyclohexane, 2.) 55 deg C, 3.5 h
2: 57.3 percent / t-BuOK / dimethylsulfoxide / 3 h / Ambient temperature
View Scheme
参考文献
Okazaki, Renji; O-oka, Masaharu; Tokitoh, Norihiro; Inamoto, Naoki
Journal of Organic Chemistry, 1985 , vol. 50, # 2 p. 180 - 185
反应条件
1: 75 percent / KO-t-Bu / pentane / 1.) -20 deg C, 1 h; 2.) room temp., 20 h
2: 40 percent / KO-t-Bu / dimethylsulfoxide / 0.5 h
View Scheme
参考文献
Davalian, Dariush; Garratt, Peter J.; Koller, Wolfgang; Mansuri, Muzammil M.
Journal of Organic Chemistry, 1980 , vol. 45, # 21 p. 4183 - 4193
反应条件
1: 36 percent / 50percent NaOH, TEBA / H2O; ethanol / 1) 1 h, 0 deg C, 2) 1 h, r.t.
2: 33 percent / KtBuO / dimethylsulfoxide / 1 h / Ambient temperature
View Scheme
参考文献
Neidlein, Richard; Poignee, Volker
Chemische Berichte, 1988 , vol. 121, p. 1199 - 1200
参考文献
Suzzarini, Laurence; Lin, Jian; Wang, Zhi Yuan
Tetrahedron Letters, 1998 , vol. 39, # 13 p. 1695 - 1696
反应条件
arc generated carbon; labelled benzene was investigated; C-H insertion reaction is exothermic by over 100 kcal/mol; Product distributionMechanism;
参考文献
Biesiada, Keith A.; Koch, Charles T.; Shevlin, Philip B.
Journal of the American Chemical Society, 1980 , vol. 102, # 6 p. 2098 - 2100
反应条件
in hexane
2 h; Irradiation;
参考文献
Chai, Christina L. L.; Christen, Detlev; Halton, Brian; Neidlein, Richard; Starr, Malcolm A. E.
Australian Journal of Chemistry, 1995 , vol. 48, # 3 p. 577 - 592
反应条件
in hexane
2 h; Irradiation;
参考文献
Chai, Christina L. L.; Christen, Detlev; Halton, Brian; Neidlein, Richard; Starr, Malcolm A. E.
Australian Journal of Chemistry, 1995 , vol. 48, # 3 p. 577 - 592
反应条件
silver tetrafluoroborate
参考文献
Billups,W.E. et al.
Journal of the American Chemical Society, 1974 , vol. 96, # 6 p. 1979 - 1980
反应条件
Yield given. Multistep reaction;
参考文献
Halton, Brian; Buckland, Simon J.; Mei, Qiu; Stang, Peter J.
Tetrahedron Letters, 1986 , vol. 27, # 42 p. 5159 - 5160
