in acetonitrile T=25°C; 17.5 h;

1: T=20°C; 3 h; 2: With ammonium chloride in dichloromethane T=20°C; 0.25 h;

chiral salicylidene imine derivative in toluene T=-70°C; Addition; Hydrocyanation; 20 h;

1: bis(N-2,6-diisopropylphenyl(phenyl)amidate)titanium-bis(diethylamido) / benzene / 8 h / 20 - 65 °C / |Schlenk technique; |Glovebox; |Inert atmosphere 2: benzene / 3 h / 20 °C / |Schlenk technique; |Glovebox; |Inert atmosphere View Scheme

1: bis(N-2,6-diisopropylphenyl(phenyl)amidate)titanium-bis(diethylamido) / benzene / 8 h / 20 - 65 °C / |Schlenk technique; |Glovebox; |Inert atmosphere 2: benzene / 3 h / 20 °C / |Schlenk technique; |Glovebox; |Inert atmosphere View Scheme

ammonium chloride