1.1: magnesium / tetrahydrofuran / |Reflux
1.2: 20 °C / |Reflux
2.1: pyridine; 1,8-diazabicyclo[5.4.0]undec-7-ene; trichlorophosphate / 0 - 80 °C
3.1: palladium 10 on activated carbon; hydrogen / methanol; ethyl acetate / 5 h / 30003 Torr
4.1: sulfuric acid / tetrahydrofuran; water / 1.5 h
View Scheme
参考文献
Zhou, Lin; Liu, Xiaohua; Ji, Jie; Zhang, Yuheng; Hu, Xiaolei; Lin, Lili; Feng, Xiaoming
Journal of the American Chemical Society, 2012 , vol. 134, # 41 p. 17023 - 17026
1: C27H33Al*C4H8O With palladium diacetate; tri-cyclo-hexyl-phosphine in toluene
T=100°C; 1 h;
2: 1-bromo-4-fluorobenzene in toluene
T=40°C; 5 h; Further stages.;
参考文献
Ku, Shih-Lun; Hui, Xin-Ping; Chen, Chien-An; Kuo, Yi-Ying; Gau, Han-Mou
Chemical Communications, 2007 , # 37 p. 3847 - 3849