1,4-双(三甲硅基)-1,3-丁二炔合成路线 (共 93 条)
反应条件
N-iodo-succinimide; silver nitrate in acetone
T=20°C; 4 h;
参考文献
Luo, Liang; Wilhelm, Christopher; Sun, Aiwu; Grey, Clare P.; Lauher, Joseph W.; Goroff, Nancy S.
Journal of the American Chemical Society, 2008 , vol. 130, # 24 p. 7702 - 7709
反应条件
1: 1,4-bis(trimethylsilyl)-1,3-butadiyne With methyllithium; lithium bromide in diethyl ether
T=20°C; 8 h;
2: formaldehyd in diethyl ether
T=0 - 20°C;
参考文献
Fiandanese, Vito; Bottalico, Daniela; Marchese, Giuseppe; Punzi, Angela
Journal of Organometallic Chemistry, 2005 , vol. 690, # 12 p. 3004 - 3008
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
T=80°C; 3 h;
参考文献
Gevorgyan, Vladimir; Quan, Long Guo; Yamamoto, Yoshinori
Journal of Organic Chemistry, 1998 , vol. 63, # 4 p. 1244 - 1247