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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
1,1-乙二醇
合成路线
（共 10 条）
64-19-7
醋酸
→
反应条件
4433-56-1
1,1-乙二醇
反应条件
rabbit 3-hydroxyhexobarbital dehydrogenase (AKR1C29); NADPH in aq. phosphate buffer; ethyl acetate T=37°C; pH=7.4; 0.5 h; Enzymatic reaction; Catalytic behaviorKinetics;
参考文献
Endo, Satoshi; Matsunaga, Toshiyuki; Matsumoto, Atsuko; Arai, Yuki; Ohno, Satoshi; El-Kabbani, Ossama; Tajima, Kazuo; Bunai, Yasuo; Yamano, Shigeru; Hara, Akira; Kitade, Yukio
Biochemical Pharmacology, 2013 , vol. 86, # 9 p. 1366 - 1375
75-07-0
乙醛
→
反应条件
4433-56-1
1,1-乙二醇
反应条件
(ZnII-(1,5,9-triazacyclododecane)(OH))3*(ClO4)3; water T=0°C; var. pH; Rate constant;
参考文献
Kimura, Eiichi; Shiota, Takeshi; Koike, Tohru; Shiro, Motoo; Kodama, Mutsuo
Journal of the American Chemical Society, 1990 , vol. 112, # 15 p. 5805 - 5811
75-07-0
乙醛
→
反应条件
64-17-5
乙醇
+
4433-56-1
1,1-乙二醇
+
64-19-7
醋酸
反应条件
sodium phosphate buffer; β-NADP+; Saccharomyces cerevisiae ADH in water-d2 T=20°C; pH=8.8; Product distribution; Further Variations:CatalystspH-valuesTemperatures;
参考文献
Velonia, Kelly; Smonou, Ioulia
Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 14 p. 2283 - 2287
78-97-7
乳腈
→
反应条件
4433-56-1
1,1-乙二醇
+
65687-54-9
+
75-07-0
乙醛
反应条件
sodium dihydrogen phosphate dihydrate; sodium hydrosulfide hydrate; water; copper (I) cyanide in water-d2 pH=6.8 - 7; 2 h; IrradiationInert atmosphere;
参考文献
Ritson, Dougal J.; Sutherland, John D.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 22 p. 5845 - 5847
Angew. Chem., 2013 , vol. 125, # 22 p. 5957 - 5959,3
64-17-5
乙醇
→
反应条件
79-14-1
羟基乙酸
+
4433-56-1
1,1-乙二醇
+
124-38-9
二氧化碳
+
107-21-1
乙二醇
+
64-19-7
醋酸
+
107-07-3
2-氯乙醇
反应条件
disodium hexachloroplatinum(IV); Cl4Pt*2Na(1+) T=120°C; 3 h; other alkyl and 13C labeled alcohols; Product distribution;
参考文献
Labinger, Jay A.; Herring, Andrew M.; Bercaw, John E.
Journal of the American Chemical Society, 1990 , vol. 112, # 14 p. 5628 - 5629
141-46-8
羟乙醛
→
反应条件
4433-56-1
1,1-乙二醇
+
69470-43-5
+
40460-44-4
+
75-07-0
乙醛
反应条件
sodium dihydrogen phosphate dihydrate; sodium hydrosulfide hydrate; water; potassium thioacyanate; copper (I) cyanide in water-d2 pH=6.8 - 7; 2 h; IrradiationInert atmosphere; Reagent/catalystTime;
参考文献
Ritson, Dougal J.; Sutherland, John D.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 22 p. 5845 - 5847
Angew. Chem., 2013 , vol. 125, # 22 p. 5957 - 5959,3
107-16-4
→
反应条件
4433-56-1
1,1-乙二醇
+
40460-44-4
+
75-07-0
乙醛
+
22322-29-8
反应条件
sodium dihydrogen phosphate dihydrate; sodium hydrosulfide hydrate; water; copper (I) cyanide in water-d2 pH=6.8 - 7; 2 h; IrradiationInert atmosphere;
参考文献
Ritson, Dougal J.; Sutherland, John D.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 22 p. 5845 - 5847
Angew. Chem., 2013 , vol. 125, # 22 p. 5957 - 5959,3
64-17-5
乙醇
→
反应条件
4433-56-1
1,1-乙二醇
+
7518-70-9
+
75-07-0
乙醛
+
64-19-7
醋酸
+
141-78-6
反应条件
oxygen T=80°C; Electrochemical reaction;
参考文献
Kim, In; Han, Oc Hee; Chae, Seen Ae; Paik, Younkee; Kwon, Sung-Hyea; Lee, Kug-Seung; Sung, Yung-Eun; Kim, Hasuck
Angewandte Chemie - International Edition, 2011 , vol. 50, # 10 p. 2270 - 2274
107-16-4
→
反应条件
4433-56-1
1,1-乙二醇
+
69470-43-5
+
40460-44-4
+
75-07-0
乙醛
+
22322-29-8
反应条件
sodium dihydrogen phosphate dihydrate; sodium hydrosulfide hydrate; water in water-d2 pH=6.8 - 7; 6 h; IrradiationInert atmosphere;
参考文献
Ritson, Dougal J.; Sutherland, John D.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 22 p. 5845 - 5847
Angew. Chem., 2013 , vol. 125, # 22 p. 5957 - 5959,3
184765-22-8
→
反应条件
4433-56-1
1,1-乙二醇
+
75-07-0
乙醛
+
85-61-0
反应条件
phosphate buffer in water; water-d2 Equilibrium constant;
参考文献
Schwartz, Benjamin; Vogel, Kurt W.; Drueckhammer, Dale G.
Journal of Organic Chemistry, 1996 , vol. 61, # 26 p. 9356 - 9361
