potassium iodide; potassium acetate in acetic acid; acetone

potassium hydroxide in tetrahydrofuran; ethanol

Al tri-t-BuO-; acetone; benzene

hydrogenchloride

ammonia unter Zusatz von Aceton;

RuCl2(η-C6H6)(TPPMS); benzoic acid in water T=100°C; 60 h; Inert atmosphere;

1: 98 percent / trimethyl orthoformate, p-toluenesulfonic acid / methanol / 3 h / 50 °C 2: H2, triphenylphosphine, rhodium acetate dimer / ethyl acetate / 20 h / 80 °C / 9000.7 Torr 3: 100 percent / N-methylmorpholine N-oxide (NMO), RuCl2(Ph3P)3 / dimethylformamide / 0.17 h 4: 97 percent / 6 N HCl / tetrahydrofuran / 0.5 h 5: 70 percent / p-chloranil / 2-methyl-propan-2-ol / Heating View Scheme

trifluoroacetic acid; [Ru(η3-2-C3H4Me)(CO)(1,1'-(Ph2P)2-ferrocene)][SbF6] in tetrahydrofuran Rupe rearrangement; 26 h; Heating;

anschliessendes Behandeln mit Na2S in wss.Aethanol und Ansaeuern des Reaktionsgemisches mit Essigsaeure;

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