三（三甲代甲硅烷基）硼酸盐合成路线 （共 14 条）
反应条件
boric acid T=110°C; 1 h;
参考文献
Voronkov; Basenko; Mirskov; Adamovich
Russian Journal of Applied Chemistry, 2006 , vol. 79, # 10 p. 1721 - 1722
反应条件
in neat (no solvent) byproducts: NH3; heating (70-85°C, then 110-120°C, several h); distn. (vac.);
参考文献
Voronkov, M. G.; Mirskov, R. G.; Chernova, V. G.; Ivanova, N. P.
Journal of General Chemistry USSR (English Translation), 1981 , vol. 51, p. 1430 - 1430
Zhurnal Obshchei Khimii, 1981 , vol. 51, p. 1678 - 1678
反应条件
in further solvent(s) byproducts: MeCOOH; mixt. of trimethylacetoxysilane and finely ground boric acid heated at 110°C for 1 h; residue distilled in vac.; elem. anal.;
参考文献
Voronkov; Basenko; Mirskov; Adamovich
Russian Journal of Applied Chemistry, 2006 , vol. 79, # 10 p. 1721 - 1722
参考文献
Shapatin,A.S. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1969 , vol. 39, p. 554 - 556,523 - 524
反应条件
in 1,2,2-trifluoro-trichloroethane 1.) 0 to 55 deg C very slowly, 2.) sonication, reflux, 16-17 h;
参考文献
Olah; Wu
Synthesis, 1991 , # 3 p. 204 - 206
参考文献
Gen.Electric Co.
Patent: US2440101 , 1947 ;
反应条件
diboron trioxide; sulfuric acid
参考文献
Mileshkevich,V.P.; Karlin,A.V.
J. Gen. Chem. USSR (Engl. Transl.), 1970 , vol. 40, p. 2573 - 2577,2565 - 2568
反应条件
in neat (no solvent) boiling of (CH3)3Si(OC2H5) and H3BO3 (3:1 mol) with p-toluenesulfonic acid as catalyst for several hours;;
参考文献
Gmelin Handbook: Si: MVol.C, 66, page 184 - 185
Full Text Show Details
British Thomson-Houston Co.
Patent: GB643298 , 1950 ;
C. A., 1951 , p. 7819
反应条件
in neat (no solvent) Me3SiCl, Me3SiOSiMe3 and 2-propanol stirred for 30 min, boric acid added and stirred for 3 h; soln. filtered and concd., mixt. analysed by using combined gas chromatograph-mass spectroscopy;
参考文献
Wada, Hiroaki; Araki, Shunji; Kuroda, Kazuyuki; Kato, Chuzo
Polyhedron, 1985 , vol. 4, p. 653 - 656
反应条件
sulfuric acid in n-heptane 3 h; Heating;
参考文献
Voronkov; Roman; Maletina
Russian Journal of General Chemistry, 1997 , vol. 67, # 7 p. 1047 - 1048
