1-[(三甲基锡烷基)甲基]苯合成路线 （共 28 条）
反应条件
iodine in methanol Kinetics; mixture was left in the dark overnight at 298 K; poured into water, extrd. (CCl4), dried (Na2SO4), NMR;
参考文献
Bulletin des Societes Chimiques Belges, , vol. 89, # 10 p. 819 - 830
反应条件
Mg in tetrahydrofuran
under high-vac. techniques; mixt. of bromobenzene, C6H5CH2SnMe3 and Mg in THF stirred for 26 h at room temp.; quenched with Me3GeCl; Et2O added; org. and aq. fractions sepd.; org. fraction dried (MgSO4); analyzed by NMR; sepd. by chromy.;
参考文献
Van Klink, Gerard P.M.; De Boer, Henricus J.R.; Schat, Gerrit; Akkerman, Otto S.; Bickelhaupt, Friedrich; Spek, Anthony L.
Organometallics, 2002 , vol. 21, # 10 p. 2119 - 2135
反应条件
bromobenzene; magnesium in tetrahydrofuran
reaction of stannane with PhBr/Mg, then with excess Me3GeCl;
参考文献
Boer, Henricus J. R. de; Akkerman, Otto S.; Bickelhaupt, Friedrich
Angewandte Chemie, 1988 , vol. 100, p. 735 - 737
反应条件
in acetonitrile
Irradiation;
参考文献
Takuwa, Akio; Nishigaichi, Yutaka; Yamashita, Koichi; Iwamoto, Hidetoshi
Chemistry Letters, 1990 , # 4 p. 639 - 642
反应条件
Mg in tetrahydrofuran
under high-vac. techniques; mixt. of bromobenzene, C6H5CH2SnMe3 and Mg in THF stirred for 26 h at room temp.; quenched with Me3GeCl; Et2O added; org. and aq. fractions sepd.; org. fraction dried (MgSO4); analyzed by NMR; sepd. by chromy.;
参考文献
Van Klink, Gerard P.M.; De Boer, Henricus J.R.; Schat, Gerrit; Akkerman, Otto S.; Bickelhaupt, Friedrich; Spek, Anthony L.
Organometallics, 2002 , vol. 21, # 10 p. 2119 - 2135
反应条件
Sm; hexamethylphosphoramide; NaHCO3 in tetrahydrofuran
mixt. of Sm, CH2I2 and THF stirred at room temp. for 2 h; (Me2N)3PO added ; soln. stirred for 10 min; C6H5(CH2SnMe3) added; after 10 min bromobenzene added; after 1 h mixt. quenched with satd. aq. NaHCO3; extd. (Et2O); combined org. layers dried (MgSO4); filtered; evapd. to dryness; purifn. by filtration through column Florisil (pentane as eluent); solvent evapd.; monitored by NMR, GCMS;
参考文献
Van Klink, Gerard P.M.; De Boer, Henricus J.R.; Schat, Gerrit; Akkerman, Otto S.; Bickelhaupt, Friedrich; Spek, Anthony L.
Organometallics, 2002 , vol. 21, # 10 p. 2119 - 2135
反应条件
bromobenzene; magnesium in tetrahydrofuran
reaction of stannane with PhBr/Mg, then with excess Me3GeCl;
参考文献
Boer, Henricus J. R. de; Akkerman, Otto S.; Bickelhaupt, Friedrich
Angewandte Chemie, 1988 , vol. 100, p. 735 - 737
反应条件
in acetonitrile
Ambient temperatureIrradiation; Yield given. Yields of byproduct given;
参考文献
Takuwa, Akio; Nishigaichi, Yutaka; Yamashita, Koichi; Iwamoto, Hidetoshi
Chemistry Letters, 1990 , # 9 p. 1761 - 1764
