1,1,1-三氟-2-丁醇合成路线 （共 10 条）
反应条件
sodium dichromate; sulfuric acid; water
参考文献
Sykes et al.
Journal of the Chemical Society, 1956 , p. 835,839
反应条件
formic acid; tetrabutylammomium bromide; water; potassium formiate; RuCl[(R,R)-Tsdpen](mesitylene)
T=30°C; 21 h; Inert atmosphereAutoclave;
参考文献
Kanto Kagaku Kabushiki Kaisha
Patent: EP2399895 A2, 2011 ;
Location in patent: Page/Page column 14 ;
反应条件
hydrogen; palladium on activated charcoal in methanol
参考文献
Pegolotti,J.A.; Young,W.G.
Journal of the American Chemical Society, 1961 , vol. 83, p. 3258 - 3262
参考文献
McBee et al.
Journal of the American Chemical Society, 1956 , vol. 78, p. 3851,3853
参考文献
Pierce et al.
Journal of the American Chemical Society, 1953 , vol. 75, p. 6324
参考文献
Campbell et al.
Journal of the American Chemical Society, 1950 , vol. 72, p. 4380,4382
参考文献
Pierce et al.
Journal of the American Chemical Society, 1953 , vol. 75, p. 6324
反应条件
hydrogen cation
1) CH2Cl2, -20 to 5 deg C, 2) H2O; Multistep reaction;
参考文献
Kuchin, A. V.; Homutov, O. G.; Filyakova, V. I.; Paschkevich, K. I.
Journal of Fluorine Chemistry, 1991 , vol. 54, # 1-3 p. 220
反应条件
hydrogen cation
1) CH2Cl2, -20 to 5 deg C, 2) H2O; Multistep reaction;
参考文献
Kuchin, A. V.; Homutov, O. G.; Filyakova, V. I.; Paschkevich, K. I.
Journal of Fluorine Chemistry, 1991 , vol. 54, # 1-3 p. 220
反应条件
sodium nitrite in perchloric acid
pH: 3.5 - 2.8; Product distributionMechanism;
参考文献
Gassen, Karl-Rudolf; Kirmse, Wolfgang
Chemische Berichte, 1986 , vol. 119, # 7 p. 2233 - 2248
