三甲基(对甲苯乙炔)硅烷合成路线 （共 36 条）
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
T=65°C; 4 h;
参考文献
Gevorgyan, Vladimir; Takeda, Akira; Homma, Miyako; Sadayori, Naoki; Radhakrishnan, Ukkiramapandian; Yamamoto, Yoshinori
Journal of the American Chemical Society, 1999 , vol. 121, # 27 p. 6391 - 6402
反应条件
1: 4-methyl phenyl acetylene With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 1 h;
2: chloro-trimethyl-silane in tetrahydrofuran
T=-78 - 20°C; 0.0583333 h;
参考文献
Huang, Hanchu; Zhang, Guojin; Gong, Li; Zhang, Shuaiyan; Chen, Yiyun
Journal of the American Chemical Society, 2014 , vol. 136, # 6 p. 2280 - 2283
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; ethylene glycol dimethyl ether; hexane
T=80°C; Arylation; Suzuki-Miyaura cross-coupling reaction; 5 h;
参考文献
Castanet, Anne-Sophie; Colobert, Francoise; Schlama, Thierry
Organic Letters, 2000 , vol. 2, # 23 p. 3559 - 3561
反应条件
1: trimethylsilylacetylene With n-butyllithium; tri-isopropoxy-borane in ethylene glycol dimethyl ether; hexane
T=-78 - 20°C; 3.5 h;
2: para-bromotoluene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; ethylene glycol dimethyl ether
16 h; Heating;
参考文献
Colobert, Francoise; Castanet, Anne-Sophie; Abillard, Olivier
European Journal of Organic Chemistry, 2005 , # 15 p. 3334 - 3341
反应条件
T=140°C; P=0.01 Torr;
参考文献
Schneider, Klaus; Daucher, Birgit; Fronda, Antonio; Maas, Gerhard
Chemische Berichte, 1990 , vol. 123, p. 589 - 594
反应条件
1: 1,2-dimethoxy-ethane; tetrahydrofuran; hexane / 2.5 h / -78 - 20 °C
2: 55 percent / Pd(PPh3)4 / 1,2-dimethoxy-ethane; tetrahydrofuran; hexane / 5 h / 80 °C
View Scheme
参考文献
Castanet, Anne-Sophie; Colobert, Francoise; Schlama, Thierry
Organic Letters, 2000 , vol. 2, # 23 p. 3559 - 3561
反应条件
tetrakis(triphenylphosphine) palladium(0)
参考文献
Negishi,E.; Takahashi,T.
Journal of the American Chemical Society, 1986 , vol. 108, p. 3402
反应条件
1: 85 percent / bromine, AIBN / CHCl3 / 0.5 h / Irradiation
2: 96 percent / NaHCO3 / acetone / 8 h / Heating
3: 1) n-BuLi
View Scheme
参考文献
Paquette, Leo A.; Fristad, William E.; Dime, David S.; Bailey, Thomas R.
Journal of Organic Chemistry, 1980 , vol. 45, # 15 p. 3017 - 3028
反应条件
1: 96 percent / NaHCO3 / acetone / 8 h / Heating
2: 1) n-BuLi
View Scheme
参考文献
Paquette, Leo A.; Fristad, William E.; Dime, David S.; Bailey, Thomas R.
Journal of Organic Chemistry, 1980 , vol. 45, # 15 p. 3017 - 3028
反应条件
palladium
Sonogashira coupling;
参考文献
Atienza; Mateo; de Frutos; Echavarren
Organic letters, 2001 , vol. 3, # 2 p. 153 - 155
