1,1-二苯基-1,3-丁二烯合成路线 （共 34 条）
反应条件
bis(η3-allyl-μ-chloropalladium(II)); (3aR,8bS)-2-lt;2-(diphenylphosphino)phenylgt;-3a,8b-dihydro-4,4-dimethyl-4H-indenollt;1,2-dgt;oxazole in tetrahydrofuran
T=60°C; 6 h; Product distribution;
参考文献
Sudo, Atsushi; Saigo, Kazuhiko
Journal of Organic Chemistry, 1997 , vol. 62, # 16 p. 5508 - 5513
参考文献
Cheminat,B.
Bulletin de la Societe Chimique de France, 1972 , p. 3415 - 3421
反应条件
2: aq. HCl
View Scheme
参考文献
Cheminat,B.
Bulletin de la Societe Chimique de France, 1972 , p. 3415 - 3421
反应条件
1: aq. HCl, AcOH
2: (i) MeI, (ii) aq. NaOH
View Scheme
参考文献
Holm,T.
Acta Chemica Scandinavica (1947-1973), 1963 , vol. 17, p. 2437 - 2443
反应条件
in deuterated toluene
heating of a sealed NMR tube with Ti-complex and cyclopropane at 70°C for 1 h; monitored by (1)H NMR;
参考文献
Mashima, Kazushi; Sakai, Nozomu; Takaya, Hidemasa
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 8 p. 2475 - 2483
反应条件
tetrahydrofuran; diethyl ether
Erwaermen des nach der Hydrolyse erhaltenen Reaktionsprodukts;
参考文献
Normant; Maitte
Bulletin de la Societe Chimique de France, 1956 , p. 951,954
反应条件
potassium acetate; acetic anhydride; acetic acid
T=127 - 142.2°C; Kinetics;
参考文献
Michejda,C.J.; Comnick,R.W.
Journal of Organic Chemistry, 1975 , vol. 40, # 8 p. 1046 - 1050
反应条件
bis(η3-allyl-μ-chloropalladium(II)); (3aR,8bS)-2-lt;2-(diphenylphosphino)phenylgt;-3a,8b-dihydro-4,4-dimethyl-4H-indenollt;1,2-dgt;oxazole; acetic acid in tetrahydrofuran
3 h; Heatingother reaction time, effect of absence of AcOH and amount of amine; Product distribution;
参考文献
Sudo, Atsushi; Saigo, Kazuhiko
Journal of Organic Chemistry, 1997 , vol. 62, # 16 p. 5508 - 5513
反应条件
(i) MeI, (ii) aq. NaOH; Multistep reaction;
参考文献
Holm,T.
Acta Chemica Scandinavica (1947-1973), 1963 , vol. 17, p. 2437 - 2443
反应条件
in pentane
Ambient temperatureIrradiation; Quantum yieldMechanismRate constant;
参考文献
Zimmerman, Howard E.; Carpenter, Clint W.
Journal of Organic Chemistry, 1988 , vol. 53, # 14 p. 3298 - 3305
