(三甲基硅基)乙酸乙酯合成路线 （共 118 条）
反应条件
T=360°C; other temperature; Rate constant;
参考文献
Taylor, Roger
Journal of the Chemical Society, Chemical Communications, 1987 , p. 741 - 742
反应条件
borane-THF in tetrahydrofuran 48 h; Ambient temperature;
参考文献
Rosowsky, Andre; Wright, Joel E.
Journal of Organic Chemistry, 1983 , vol. 48, # 9 p. 1539 - 1541
反应条件
1: 78.1 percent / BH3*THF / tetrahydrofuran / 48 h / Ambient temperature 2: 87 percent / CH2Cl2; pyridine / 2 h / Ambient temperature View Scheme
参考文献
Rosowsky, Andre; Wright, Joel E.
Journal of Organic Chemistry, 1983 , vol. 48, # 9 p. 1539 - 1541
反应条件
t-Bu-N=P[N=P(NMe2)3]3 in tetrahydrofuran; hexane T=-78°C; Peterson olefination; 6 h;
参考文献
Kobayashi, Koji; Ueno, Masahiro; Kondo, Yoshinori
Chemical Communications, 2006 , # 29 p. 3128 - 3130
反应条件
lithium diisopropyl amide 1.) THF, hexane, -78 deg C, 1 h, 2.) a) from -78 deg C to room temp., 1 h, b) room temp., 2 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tsuge, Otohiko; Sone, Kazuhiro; Urano, Satoshi; Matsuda, Koyo
Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5171 - 5177
反应条件
tetrabutyl ammonium fluoride; fluorine 1.) CH2Cl2, -50 deg C, 2.) CH2Cl2, a) -50 deg C, 1 h, b) -50 to 0 deg C, 1 h, c) 0 deg C, 0.5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kiselyov, Alexander S.; Strekowski, Lucjan
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4476 - 4478
反应条件
sulfuric acid 1.)ethyl trimethylsilylacetate, ether, -78 grad C, warmed to rt., stirred overnight, 2.) THF/conc. H2SO4, 15 h; Yield given. Multistep reaction;
参考文献
Larson, Gerald L.; Hernandez, David
Tetrahedron Letters, 1982 , vol. 23, # 10 p. 1035 - 1038
反应条件
tetrabutylammonium fluoride absorbed on silica gel in tetrahydrofuran 3 h; Ambient temperature;
参考文献
Synthetic Communications, , vol. 19, # 13-14 p. 2441 - 2448
反应条件
t-Bu-N=P[N=P(NMe2)3]3 in tetrahydrofuran; hexane T=-78°C; Peterson olefination; 6 h;
参考文献
Kobayashi, Koji; Ueno, Masahiro; Kondo, Yoshinori
Chemical Communications, 2006 , # 29 p. 3128 - 3130
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; magnesium bromide; lithium diisopropyl amide in tetrahydrofuran T=0°C; 0.5 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Larcheveque, Marc; Debal, Alain
Journal of the Chemical Society, Chemical Communications, 1981 , # 17 p. 877 - 878
