N,N-二甲基-2-氟苯胺合成路线 （共 10 条）
反应条件
1: (i) aq. HCl, (ii) aq. NaNO2, (iii) /BRN= 2078394/, aq. HCl 2: Al, aq. HCl 3: AcOH View Scheme
参考文献
van Loon,A. et al.
Recueil des Travaux Chimiques des Pays-Bas, 1960 , vol. 79, p. 977 - 1001
反应条件
N-fluoro-N-(phenylsulfonyl)benzene-sulfonamide in chloroform
T=25°C; 10 h; TimeTemperatureReagent/catalyst;
参考文献
Sorokin, Vladimir I.; Pozharskii, Alexander F.; Ozeryanskii, Valery A.
Journal of Fluorine Chemistry, 2013 , vol. 154, p. 67 - 72
反应条件
1: With diisobutylaluminium hydride; magnesium; lithium chloride in tetrahydrofuran
T=0 - 25°C; Inert atmosphere;
2: With N-fluoro-N-(phenylsulfonyl)benzene-sulfonamide in dichloromethane; perfluorodecahydronaphthalene
T=-78 - 25°C; Inert atmosphere;
参考文献
Yamada, Shigeyuki; Knochel, Paul
Synthesis, 2010 , # 14 art. no. T09010SS, p. 2490 - 2494
反应条件
zirconium tetrachloride; N-fluoro-N-(phenylsulfonyl)benzene-sulfonamide in chloroform
5 h; Reflux;
参考文献
Sorokin, Vladimir I.; Pozharskii, Alexander F.; Ozeryanskii, Valery A.
Journal of Fluorine Chemistry, 2013 , vol. 154, p. 67 - 72
反应条件
Ru(Triphos)(TMM); hydrogen; bis-(trifluoromethylsulphonyl)amine in tetrahydrofuran
T=150°C; P=60006 Torr; 24 h; AutoclaveInert atmosphere;
参考文献
Beydoun, Kassem; Vom Stein, Thorsten; Klankermayer, Juergen; Leitner, Walter
Angewandte Chemie - International Edition, 2013 , vol. 52, # 36 p. 9554 - 9557
Angew. Chem., 2013 , vol. 125, # 36 p. 9733 - 9736
参考文献
Evans; Williams
Journal of the Chemical Society, 1939 , p. 1199
反应条件
1: aqueous sodium carbonate
2: 210 °C
View Scheme
参考文献
v.Braun; Rudolph
Chemische Berichte, 1931 , vol. 64, p. 2465,2472
参考文献
v.Braun; Rudolph
Chemische Berichte, 1931 , vol. 64, p. 2465,2472
反应条件
T=58.4 - 90.9°C; Rate constant;
参考文献
Bevan; Byer
Journal of the Chemical Society, 1957 , p. 3194,3196
反应条件
1: (i) aq. HCl, (ii) aq. NaNO2, (iii) /BRN= 2078394/, aq. HCl
2: Al, aq. HCl
View Scheme
参考文献
van Loon,A. et al.
Recueil des Travaux Chimiques des Pays-Bas, 1960 , vol. 79, p. 977 - 1001
