1-三甲基硅烷-1-己炔合成路线 （共 85 条）
反应条件
1: 97 percent / HSiCl3, H2PtCl6*6H2O / 6 h / Heating
2: 76 percent / ZnF2*4H2O / Ambient temperature
3: 56 percent / MCPBA / dimethylformamide / 1 h / -50 °C
View Scheme
参考文献
Tamao, Kohei; Akita, Munetaka; Kumada, Makoto
Journal of Organometallic Chemistry, 1983 , vol. 254, # 1 p. 13 - 22
反应条件
1: 1) DIBAH, 2) I2 / 1) Et2O, hexane, a) r.t., 0.5 h, b) 40 deg C, 1 h, 2) Et2O, -78 deg C, 1 h
2: NaOMe / methanol / 4 h / 40 °C
4: 78 percent / acetonitrile / 24 h / Heating
6: 80 percent / Py / tetrahydrofuran / 1) -20 deg C, 0.5 h, 2) r.t., 3 h
View Scheme
参考文献
Bestmann; Zeibig; Vostrowsky
Synthesis, 1990 , # 11 p. 1039 - 1047
反应条件
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Wang, Kung K.; Nikam, Sham S.; Ho, Chihmei D.
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5376 - 5377
反应条件
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Wang, Kung K.; Nikam, Sham S.; Ho, Chihmei D.
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5376 - 5377
反应条件
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Wang, Kung K.; Nikam, Sham S.; Ho, Chihmei D.
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5376 - 5377
反应条件
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Wang, Kung K.; Nikam, Sham S.; Ho, Chihmei D.
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5376 - 5377
反应条件
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Wang, Kung K.; Nikam, Sham S.; Ho, Chihmei D.
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5376 - 5377
反应条件
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Wang, Kung K.; Nikam, Sham S.; Ho, Chihmei D.
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5376 - 5377
反应条件
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Wang, Kung K.; Nikam, Sham S.; Ho, Chihmei D.
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5376 - 5377
反应条件
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Wang, Kung K.; Nikam, Sham S.; Ho, Chihmei D.
Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5376 - 5377
