1-三甲基硅烷-1-己炔合成路线 （共 85 条）
反应条件
aluminium trichloride in carbon disulfide
参考文献
Birkofer,L. et al.
Chemische Berichte, 1963 , vol. 96, p. 3280 - 3288
反应条件
in tetrahydrofuran; hexane T=-45°C; 2 h;
参考文献
Tanaka, Ken; Hagiwara, Yuji; Noguchi, Keiichi
Angewandte Chemie - International Edition, 2005 , vol. 44, # 44 p. 7260 - 7263
反应条件
fluoride gas-phase reaction; gas-phase reactions of anions with substituted silanes; Product distribution;
参考文献
DePuy, C. H.; Bierbaum, Veronica M.; Flippin, L. A.; Grabowski, Josef J.; King, Gary K.; et al.
Journal of the American Chemical Society, 1980 , vol. 102, # 15 p. 5012 - 5015
反应条件
1: 97 percent / HSiCl3, H2PtCl6*6H2O / 6 h / Heating 2: 76 percent / ZnF2*4H2O / Ambient temperature 3: MCPBA / dimethylformamide / 1 h / -50 °C View Scheme
参考文献
Tamao, Kohei; Akita, Munetaka; Kumada, Makoto
Journal of Organometallic Chemistry, 1983 , vol. 254, # 1 p. 13 - 22
反应条件
hydrogen bromide T=0°C;
参考文献
Boeckman,R.K.; Blum,D.M.
Journal of Organic Chemistry, 1974 , vol. 39, p. 3307 - 3308
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; Yb-imine; methyl iodide in tetrahydrofuran 17 h; Ambient temperature;
参考文献
Makioka, Yoshikazu; Taniguchi, Yuki; Kitamura, Tsugio; Fujiwara, Yuzo; Saiki, Akira; Takaki, Ken
Bulletin de la Societe Chimique de France, 1997 , vol. 134, # 3-4 p. 349 - 356
反应条件
1: 1.) i-BuMgBr, Cp2TiCl2 2: 91 percent / Ti(Oi-Pr)4, L(+)DET 3: 80 percent / CrO3, pyridine 4: diethyl ether / -78 - 0 °C 5: 85 percent / AlH3 / diethyl ether 6: H2SO4 / methanol / 0.5 h / -10 - 0 °C 7: H2 View Scheme
参考文献
Takeda, Yoshiyuki; Matsumoto, Takashi; Sato, Fumie
Journal of Organic Chemistry, 1986 , vol. 51, # 24 p. 4728 - 4731
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; Yb-imine; methyl iodide in tetrahydrofuran 17 h; Ambient temperature;
参考文献
Bulletin de la Societe Chimique de France, , vol. 134, # 3-4 p. 349 - 356
反应条件
[Ni(PEt3)4] T=150°C; 24 h;
参考文献
Journal of Organometallic Chemistry, , vol. 499, # 1.2 p. 35 - 42
反应条件
methanol; potassium hydroxide in water T=0 - 25°C; 12 h; DarknessInert atmosphere;
参考文献
Teiber, Marco; Mueller, Thomas J. J.
Chemical Communications, 2012 , vol. 48, # 15 p. 2080 - 2082
