反应条件
ammonia in methanol; dichloromethane addn. of MeOH satd. with NH3 and nickel acetate to a soln. of octaethylporphyrin N-oxide in CH2Cl2, refluxing under Ar for 24 h; cooling, evapn. in vac., dissolving in CH2Cl2, washing (aq. NH3, H2O), concg. in vac., column chromy. (silica gel, hexane/CH2Cl2) gives a pink fraction of Ni-octaethylporphyrin, elution with CH2Cl2, evapn. in vac., recrystn. (CH2Cl2/MeOH), elem. anal.;
参考文献
Balch, Alan L.; Chan, Yee Wai; Olmstead, Marilyn; Renner, Mark W.
Journal of the American Chemical Society, 1985 , vol. 107, p. 2393 - 2398