2-甲基环戊并-1,3-二烯合成路线 （共 24 条）
参考文献
Roth,W.R. et al.
Chemische Berichte, 1975 , vol. 108, p. 2171 - 2175
反应条件
aluminum oxide; platinum-tin
T=500°C; P=750.06 Torr; 3 h; other catalysts; dehydroisomerisation; Product distribution;
参考文献
Wilde, M.; Feldhaus, R.; Anders, K.; Neubauer, H.-D.
Zeitschrift fuer Physikalische Chemie (Leipzig), 1990 , vol. 271, # 5 p. 919 - 925
反应条件
1: (SPY-5-31)-dichloro-(κ2(C,O)-(2-isopropyloxybenzylidene))(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)ruthenium / 0.75 h / 20 °C / Neat (no solvent); Inert atmosphere
2: monoaluminum phosphate; magnesium sulfate / 5 h / 60 °C / 40 Torr
View Scheme
参考文献
Meylemans, Heather A.; Quintana, Roxanne L.; Goldsmith, Bryan R.; Harvey, Benjamin G.
ChemSusChem, 2011 , vol. 4, # 4 p. 465 - 469
反应条件
(i) NaNH2, liq. NH3, (ii) /BRN= 969135/; Multistep reaction;
参考文献
McLean,S.; Haynes,P.
Tetrahedron, 1965 , vol. 21, p. 2313 - 2327
反应条件
Further byproducts given;
参考文献
Krimse, Wolfgang; Chiem, Pham Van; Henning, Paul-Georg
Tetrahedron, 1985 , vol. 41, # 8 p. 1441 - 1452
反应条件
Further byproducts given;
参考文献
Krimse, Wolfgang; Chiem, Pham Van; Henning, Paul-Georg
Tetrahedron, 1985 , vol. 41, # 8 p. 1441 - 1452
参考文献
Chouikin et al.
Bulletin de la Societe Chimique de France, 1957 , p. 406
反应条件
T=700°C; P=0.01 Torr; ΔI; Product distribution;
参考文献
Kagramanov, N. D.; Bragilevskii, I. O.; Mal'tsev, A. K.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1988 , vol. 37, p. 1572 - 1576
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988 , # 8 p. 1763 - 1768
反应条件
KF-70
T=250°C; other reagents, other temperatures; Product distribution;
参考文献
Safarov, M. G.; Bikkulov, R. M.; Safarova, V. G.; Rafikov, S. R.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 4 p. 789 - 791
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 4 p. 896 - 899
反应条件
T=600°C; P=20 Torr; weitere Produkte: 3-Methyl-penta-1,3-dien; Benzol; Isopren;
参考文献
Schuikin; Naryschkina
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1958 , p. 508; engl. Ausg. S. 489
