2,4-二硝基-N-(壬烷-5-亚基氨基)苯胺合成路线 （共 18 条）
反应条件
phosphonic acid diethyl ester
参考文献
Maynard,J.A.
Australian Journal of Chemistry, 1962 , vol. 15, p. 867 - 868
反应条件
1: m-chloroperbenzoic acid
2: 81 percent / butyl-lithium / hexane; tetrahydrofuran / 1 h / 0 °C
3: 69 percent / butyl-lithium / hexane; tetrahydrofuran / 0 °C
4: 86 percent / di-isobutylaluminum hydride / toluene / 48 h / Heating
5: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C
View Scheme
参考文献
Ager, David J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 195 - 204
反应条件
1: 81 percent / butyl-lithium / hexane; tetrahydrofuran / 1 h / 0 °C
2: 69 percent / butyl-lithium / hexane; tetrahydrofuran / 0 °C
3: 86 percent / di-isobutylaluminum hydride / toluene / 48 h / Heating
4: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C
View Scheme
参考文献
Ager, David J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 195 - 204
反应条件
1: 70 percent / butyl-lithium, N,N,N',N'-tetramethylethylenediamine / hexane / 1 h / -5 - 0 °C
2: acid / methanol
View Scheme
参考文献
Ager, David J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 183 - 194
反应条件
1: 1.) lithium naphthalenide / 1.) 2 h, 2.) TMEDA, room temperature
2: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C
View Scheme
参考文献
Ager, David J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 195 - 204
反应条件
1: 88 percent / m-chloroperbenzoic acid / CH2Cl2 / -23 °C
2: 69 percent / butyl-lithium / hexane; tetrahydrofuran / 0 °C
3: 86 percent / di-isobutylaluminum hydride / toluene / 48 h / Heating
4: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C
View Scheme
参考文献
Ager, David J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 195 - 204
反应条件
1: 69 percent / butyl-lithium / hexane; tetrahydrofuran / 0 °C
2: 86 percent / di-isobutylaluminum hydride / toluene / 48 h / Heating
3: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C
View Scheme
参考文献
Ager, David J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 195 - 204
反应条件
1: 1.) butyl-lithium, 2.) TMEDA / 1.) hexane, THF, 0 deg C, 1.5 h, 2.) hexane, THF, 12 h
2: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C
View Scheme
参考文献
Ager, David J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 195 - 204
反应条件
1: 1.) lithium naphthalenide
2: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C
View Scheme
参考文献
Ager, David J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 195 - 204
反应条件
1: 50 percent / butyl-lithium / hexane; tetrahydrofuran / 1 h / 0 °C
2: 86 percent / di-isobutylaluminum hydride / toluene / 48 h / Heating
3: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C
View Scheme
参考文献
Ager, David J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 195 - 204
