Prakash, G. K. Surya; Mathew, Thomas; Hoole, Dushyanthi; Esteves, Pierre M.; Wang, Qi; Rasul, Golam; Olah, George A.
Journal of the American Chemical Society, 2004 , vol. 126, # 48 p. 15770 - 15776
cobalt(III) acetate; trifluoroacetic acid; potassium iodide in water T=25°C; 0.116667 h; Mn(OAc)3 or (NH4)2Ce(SO4)3 instead Co(OAc)3; object of study: oxidative iodination promoted by Co(III), Ni(III) or Ce(IV); Product distribution;
参考文献
Journal of Organic Chemistry USSR (English Translation), , p. 1003 - 1006
Zhurnal Organicheskoi Khimii, , vol. 22, # 6 p. 1117 - 1120
sodium nitrite in dichloromethane; water mixt. of NaNO2 and the boron contg. salt in a two phase system stirred vigorously at 40°C, 2.5h (accompanied by evolution of nitrogen oxides), further product: 4-F-C6H4NO2 (traces); organic layer sepd. from aq. layer, evapn. of CH2Cl2 in vac., residue sepd. by chromy. (silica gel, hexane (9-iodo-m-carbaborane); benzene-hexane 1:1 (9-nitro-m-carbaborane); ether (9-hydroxy-m-carbaborane);
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 57, p. 1199 - 1205
Zhurnal Obshchei Khimii, , vol. 57, p. 1341 - 1347
in chloroform; water mixt. of aryl(m-carboran-9-yl)iodonium tetrafluoroborate, NaCl, water and chloroform was vigorously stirred under reflux at 56°C, 2-2.5 h; internal standard (chlorobenzene) added and org. layer was analysed by GLC;
in chloroform; water mixt. of aryl(m-carboran-9-yl)iodonium tetrafluoroborate, NaF, water and chloroform was vigorously stirred under reflux at 56°C, 1.25 h; internal standard (chlorobenzene) added and org. layer was analysed by GLC;
